نتایج جستجو برای: liquid equilibrium
تعداد نتایج: 340935 فیلتر نتایج به سال:
dynamic analysis and study of atomic force microscope in liquid environment is the main goal of this research. hydrodynamic and squeeze forces act on cantilever of atomic force microscope which works in liquid environment, so. in this paper the effect of different environmental and physical factors had studied on frequency response diagrams. the importance of frequency response analysis is stud...
We study the effects of nuclear polarization M on the liquid-gas equilibrium phase diagram of 3He, in situations where the saturating vapour pressure increases or decreases as a function of M, and where a metamagnetic instability may occur in the liquid phase. Numerical predictions are given within the frame of a phenomenological model with parameters fitted to reproduce accurately the saturati...
Theoretical calculations are presented of solid-liquid equilibrium for linear quadrupolar molecules, focusing especially on the ratio of the triple point temperature to the critical temperature. The proposed treatment uses the hard quadrupolar dumbbell model as the reference system, and incorporates the effect of dispersion forces through a mean-field term. The reference system of quadrt/polar ...
Liquid-Liquid Equilibrium (LLE) data are measured for the ternary mixtures of water + 1-butanol + butyl acetate and quaternary mixtures of water + 1-butanol + butyl acetate + glycerol at atmospheric pressure at 313.15 K. In addition, isothermal vapor–liquid–liquid equilibrium (VLLE) data are determined experimentally at 333.15 K. The region of heterogeneity is found to increase as the hydrophil...
A mathematical model for the computation of the phase equilibrium and gas-particle partitioning in atmospheric organic aerosols is presented. The thermodynamic equilibrium is determined by the global minimum of the Gibbs free energy under equality and inequality constraints for a system that involves one gas phase and many liquid phases. A primal-dual interior-point algorithm is presented for t...
We report Monte Carlo simulations that show a closed-loop liquid-vapor equilibrium in a pure substance. This finding has been achieved on a two-dimensional lattice model for patchy particles that can form network fluids. We have considered related models with a slightly different patch distribution in order to understand the features of the distribution of patches on the surface of the particle...
A simple fluid, described by pointlike particles interacting via the Lennard-Jones potential, is considered under confinement in a slit geometry between two walls at distance L_{z} apart for densities inside the vapor-liquid coexistence curve. Equilibrium then requires the coexistence of a liquid "bridge" between the two walls, and vapor in the remaining pore volume. We study this equilibrium f...
This work is mainly an investigation of some of the liquid-to-solid properties of pure benzene on a restricted domain of high pressures (20.6< or =P< or =102.9 MPa). Newly obtained equilibrium experimental data and recently developed analytical equation of state are exploited and compared with each other and with previous experimental data. Curves fitted to the pressure, volume discontinuity, a...
In this study a simple and general chemical association theory is introduced. The concept of infinite equilibrium model is re-examined and true mole fractions of associated species are calculated. The theory is applied to derive the distribution function of associated species. As a severe test the application of presented theory to the van der Waals mixture model is introduced in order to p...
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