Optimizing the heating properties of magnetic nanoparticles is of great importance for hyperthermia applications. Recent experimental results show that core/shell nanoparticles could give an increased specific absorption rate (SAR) compared to the magnetic oxide nanoparticles currently used. We have developed a modified phenomenological model based on the linear Néel-Brown relaxation model to c...

The control of the magnetization inversion dynamics is one main challenges driving design new nanostructured magnetic materials for magnetoelectronic applications. Nanoparticles with onion-like architecture offer a unique opportunity to expand possibilities allowing combine different phases at nanoscale and also modulate coupling between by introducing spacers in same structure. Here we report ...

This paper presents the experimental realization of magnetic hollow microspheres. Starting from core-shell microspheres with an organic core and a shell composed of nanoparticles, we could remove the core using a plasma etching technique. An estimate of the magnetoelastic effects arising from the interplay of magnetic dipolar interactions and cohesive energy which can be expected in such struct...

Pilot experiments were performed. Microwave induced plasma decomposition of iron pentacarbonyl has been used to prepare iron nanosized particles. Vapours of iron pantacarbonyl have been introduced into argon surfaguide discharge, optical emission spectra have been taken and rotational temperatures obtained. The rotational temperatures remain practically constant during the increasing of the Fe(...

in this work, hierarchical wo3 core-shell microspheres were synthesized via a facile template-free precipitation method. gas sensing properties of the synthesized powder to acetone and some other volatile organic compounds were comparatively investigated with commercial wo3 nanoparticles. the synthesized and commercial powders were characterized by x-ray diffraction, scanning electron microscop...

the photocatalytic coatings were prepared via incorporating the modified titania nanoparticles into epoxy-based inorganic-organic hybrid coatings. titania nanoparticles were first synthesized from tetra-n-butyl titanate using sol-gel methods by two different calcination treatments, i.e., in mild condition (80°c) and 500°c. the formed anatase nanoparticles were further modified as titania-silica...

A study of "inverted" core-shell, MnO/gamma-Mn(2)O(3), nanoparticles is presented. Crystal and magnetic structures and characteristic sizes have been determined by neutron diffraction for the antiferromagnetic core (MnO) and the ferrimagnetic shell (gamma-Mn(2)O(3)). Remarkably, while the MnO core is found to have a T_{N} not far from its bulk value, the magnetic order of the gamma-Mn(2)O(3) sh...

Imprinting nanoparticles: Core-shell bovine hemoglobin (BHb) imprinted magnetic nanoparticles (MNPs) with a mean diameter of 210 nm have been synthesized for the first time. The imprinted magnetic nanoparticles could easily reach the adsorption equilibrium and magnetic separation under an external magnetic field, thus avoiding problems related to the bulk polymer. In this work, the core-shell b...

For three types of colloidal magnetic nanocrystals, we demonstrate that postsynthetic cation exchange enables tuning of the nanocrystal's magnetic properties and achieving characteristics not obtainable by conventional synthetic routes. While the cation exchange procedure, performed in solution phase approach, was restricted so far to chalcogenide based semiconductor nanocrystals, here ferrite-...

Multifunctional core-shell nanocomposites with a magnetic core and a silica shell doped with lanthanide chelate have been prepared by a simple method. First, citric acid-modified magnetite nanoparticles were synthesized by a chemical coprecipitation method. Then the magnetite nanoparticles were coated with silica shells doped with terbium (Tb(3+)) complex by a modified Stöber method based on hy...