Post-column photochemical reaction systems have developed into a common approach for enhancing conventional methods of detection in HPLC. Photochemical reactions as a means of 'derivatization' have a significant number of advantages over chemical reaction-based methods, and a significant effort has been demonstrated to develop an efficient photochemical reactor. When coupled to electrochemical ...

© Meteoritical Society, 2002. Printed in USA. 867 Prelude preprint MS#4690 Abstract–We explore the likely production and fate of 14C in the thick nitrogen atmosphere of Saturn's moon Titan and investigate the constraints that measurements of 14C might place on Titan's photochemical, atmospheric transport and surface-atmosphere interaction processes. Titan's atmosphere is thick enough that cosmi...

Three probes for diagnosing photochemical dynamics are presented and applied to specialized ambient surface-level observations and to a numerical photochemical model to better understand rates of production and other process information in the atmosphere and in the model. However, care must be taken to ensure that rate and process information is not confounded by inappropriate averaging over th...

To better understand the photochemical processing of dicarboxylic acids and related polar compounds, we conducted batch UV irradiation experiments on two types of aerosol samples collected from India, which represent anthropogenic (AA) and biogenic (BA) aerosols, for time periods of 0.5 to 120 h. The irradiated samples were analyzed for molecular compositions of diacids, oxoacids and α-dicarbon...

Ozone data from 13 rural and 11 urban sites for the growth season (April through September) during 1990-2006 have been analysed on the basis of recently introduced photochemical pollution indicators. The indicators predict that urban sites are prone to photochemical pollution, although compared to some rural sites, the urban sites have lower average ozone concentrations and showed lower values ...

Holographic experiments are performed on a series of dual-use chromophore molecules wherein both irreversible photochromic and erasable photorefractive holographic gratings can be written in the same storage volume. At 675 nm, the chromophore undergoes a photochemical reaction leading to the creation of irreversible holographic gratings. Alternatively, at longer wavelengths, application of an e...

We conducted irradiation experiments with riverine, estuarine, and marine water samples to investigate the possibility of photochemical methane (CH4) formation. CH4 photoproduction was undetectable under oxic conditions or in the absence of methyl radical precursors indicating that its photochemical formation is negligible in the present ocean. Significant photochemical CH4 production was obser...

Research into the photochcmistry of biopolymcrs has increased in scope and scale to such an extent in recent years that it has become necessary to limit this review to a consideration of photochemical approaches to the structure of polynucleotides. Treatment proceeds from the constituent monomers to the polymer to emphasize the changes in photophysical and photochemical properties of the monome...

Methacrylate-benzodioxinone (BDMA) as a monomer was firstly synthesized and then copolymerized with methyl methacrylate 2-hydroxyethyl via atom transfer radical polymerization (ATRP) in the presence of CuCl/pentamethyldiethylene triamine (PMDETA) catalytic system using ethyl 2-bromopropionate (EtBrP) an initiator. Successful formation block copolymer also confirmed detail by proton nuclear magn...