We present new magnetic heat capacity and neutron scattering results for two magnetically frustrated molybdate pyrochlores: S=1 oxide Lu_{2}Mo_{2}O_{7} and S=1/2 oxynitride Lu_{2}Mo_{2}O_{5}N_{2}. Lu_{2}Mo_{2}O_{7} undergoes a transition to an unconventional spin glass ground state at T_{f}∼16  K. However, the preparation of the corresponding oxynitride tunes the nature of the ground state from...

   In this research, mesoporous silica was served as the host of molybdate (corrosion inhibitor). The loaded mesoporous silica was dispersed in a paint matrix. The composite was then coated on the carbon steel surface. Polarization and electrochemical impedance spectroscopy (EIS) tests showed that the corrosion resistance of the scratched paint containing molybdate loaded mesoporous silica ...

Bacillus subtilis LM 4-2, a Gram-positive bacterium was isolated from a molybdenum mine in Luoyang city. Due to its strong resistance to molybdate and potential utilization in bioremediation of molybdate-polluted area, we describe the features of this organism, as well as its complete genome sequence and annotation. The genome was composed of a circular 4,069,266 bp chromosome with average GC c...

Nitrate reductase (nar) A, B and E mutants of Escherichia coli with plasmids carrying Klebsiella pneumoniae nitrogen fixation (nif) genes reduced acetylene independently of added molybdate, but nar D mutants showed pleiotropic dependence on the concentration of added molybdate for expression of both nar and nif. No complementation of nar mutations by nif occurred; nitrite but not nitrate repres...

The iron molybdate NaMgFe(MoO4)3 {sodium magnesium iron(III) tris-[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe2(MoO4)3 and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe]2O10 units of edge-sharing [Mg,Fe]O6 octa-hedra which are linked to each other through the common corners of [MoO4] tetra-hedra. The ...

The performance of Mo-enriched, bulk ferric molybdate, employed commercially for the industrially important reaction of the selective oxidation of methanol to formaldehyde, is limited by a low surface area, typically 5-8 m(2) g(-1). Recent advances in the understanding of the iron molybdate catalyst have focused on the study of MoOx@Fe2O3 (MoOx shell, Fe2O3 core) systems, where only a few overl...

In order to reduce phosphorus pollution, the low passivation process on Q235 steel was studied. The electrochemical method used test corrosion resistance of sodium molybdate passivation. polarization curve shows that current sample passivated by is only 1/4 blank sample. Under scanning electron microscopy, film obtained treatment had lowest content and more uniform compact. XPS (X-ray photoelec...

During the screening for Rhodobacter capsulatus mutants defective in xanthine degradation, one Tn5 mutant which was able to grow with xanthine as a sole nitrogen source only in the presence of high molybdate concentrations (1 mM), a phenotype resembling Escherichia coli mogA mutants, was identified. Unexpectedly, the corresponding Tn5 insertion was located within the moeA gene. Partial DNA sequ...