The inhibition of the activity of xanthine oxidase by vanadate was strikingly similar to vanadate inhibition of another molybdoprotein nitrate reductase. Although the main catalytic activity of both enzymes was inhibited, the partial NADH oxidase activity associated with these enzymes was stimulated several fold. It appears that the metal ion binds at multiple site in both enzymes. In the absen...

The use of UHMWPE has attracted the attention of many researchers and industries. The aim of the present work is to fabricate UHMWPE/MoS2-Oxide nano-composites using in-situ polymerization. For this purpose, modified molybdenum disulfide was used. In order to perform the polymerization, a Ziegler-Natta catalytic system, with MoS2-Oxide and magnesium Ethoxide as support, was used. In order to fa...

Auger Electron Spectroscopy (AES) has been used to study the surface compositions of three types of nickel based chromium alloys. These alloys are IN600, IN601 and C22. AES analysis indicated the presence of chromium and oxygen on their surfaces. The formation of this chromium oxide surface layer, 3 nm thick, provides excellent corrosion resistance. For alloy C22, no molybdenum was indicated on...

A toluene-soluble molybdenum(vi) complex containing a bulky hydrophobic substituent, (Et4N)2[Mo(VI)O2{1,2-S2-3,6-(RCONH)2C6H2}2] (R = (4-(t)BuC6H4)3C), was dissolved in the hydrophobic core of a micelle in an aqueous medium and catalyzed the biomimetic reduction of an amine N-oxide by an NADH analog. The kinetic isotope effect of solvent water clearly indicates that water molecules are essentia...

Electrochemical water splitting is one of the most economical and sustainable methods for large-scale hydrogen production. However, the development of low-cost and earth-abundant non-noble-metal catalysts for the hydrogen evolution reaction remains a challenge. Here we report a two-dimensional coupled hybrid of molybdenum carbide and reduced graphene oxide with a ternary polyoxometalate-polypyr...

background: technetium-99m radioisotope is the backbone of any nuclear medicine institute. this radioisotope is acquired by the elution of molybdenum-99/technetium-99m generator which emits 141 kev gamma ray and having 6.04 hour half-life. occasionally the contents of molybdenum-99 may mix up with elute, which may affect image quality and patients may receive higher doses than recommended. this...

The ideal gasoline must have a high pump octane number, in the 86 to 94 range, and a low environmental impact. Alkanes, as a family, have much lower photochemical reactivities than aromatics or olefins, but only the highly branched alkanes have adequate octane numbers. The purpose of this work is to examine the possibilities of extending the technological alternative of paraffin isomerization t...

We exploit the utilization of two-dimensional (2D) molybdenum oxide nanoflakes as a co-catalyst for ZnO nanorods (NRs) to enhance their photocatalytic performance. The 2D nanoflakes of orthorhombic α-MoO3 were synthesized through a sonication-aided exfoliation technique. The 2D MoO3 nanoflakes can be further converted to substoichiometric quasi-metallic MoO3-x by using UV irradiation. Subsequen...