The reaction of Na2MoO4 with 2,2'-oxydianiline (2-aminophenylether), (2-NH2C6H4)2O, LH4, in DME (DME = 1,2-dimethoxyethane) in the presence of Et3N and Me3SiCl afforded either the bis(imido) molybdenum(vi) complex {Mo(L)Cl2(DME)} (), where L = (2-NC6H4)2O, or the molybdenum(v) salt [Mo(L')Cl4][Et3NH] (), where L' = [(2-NH2C6H4)(2-NC6H4)O], depending on the work-up method employed. The same diam...

The title mixed-alkali-metal molybdenium oxide, hexa-kis-(lithium/sodium) undeca-molybdate, was synthesized by solid-state reaction at 793 K. Its [Mo11O36](6-) framework is built up from MoO6 octa-hedra and MoO5 pyramids linked together by edges and vertices. The framework delimits two types of inter-secting tunnels running along [100] and [001], where the sodium and lithium ions are located. T...

Two new compounds containing the title diphosphono-polyoxometalate anion and diprotonated ethylenediamine (enH(2)) or piperazine (ppzH(2)) countercations have been hydrothermally synthesized and structurally characterized ((enH(2))(4)[Mo(7)O(16)(O(3)PCH(2)PO(3))(3)].7H(2)O, triclinic, P(-)1, Z = 2, a = 10.3455(7) A, b = 13.136(1) A, and c = 20.216(3) A, alpha = 93.247(6) degrees, beta = 96.434(...