Biogenic Mn-oxides (BioMnO(x)), produced by microorganisms, possess an extraordinary ability to sequester metals. BioMnO(x) are generally layered structures containing varying amounts of Mn(III) and vacant sites in the Mn layers. However the relationship between the varying structure of BioMnO(x) and metal sorption properties remains unclear. In this study, BioMnO(x) produced by Pseudomonas put...

This perspectives article takes a broad view of the current understanding of magnetic bistability and magnetic quantum tunneling in single-molecule magnets (SMMs), focusing on three families of relatively simple, low-nuclearity transition metal clusters: spin S = 4 Ni(II)(4), Mn(III)(3) (S = 2 and 6) and Mn(III)(6) (S = 4 and 12). The Mn(III) complexes are related by the fact that they contain ...

the study aimed to come up with a list of specific macroalgae species, which could be used to biomonitor specific metal elements in the coastal waters of east africa. water extraction, edta, aqua regia extraction and optimized bcr 3-step sequential extracts were used to mimic bioavailable metals under various environmental conditions. the results indicated that ulva lactuca could be used as a ...

Three isomorphous compounds M(CHOO)3[NH2(CH3)2] (M = Mn(1 x Mn), Co(2 x Co), Ni(3 x Ni)) have been synthesized in solvothermal conditions. Single-crystal X-ray diffraction shows that they are all crystallized in the trigonal space group R c with small differences in the lattice parameters. Bridged by the three-atom single-bridge CHOO-, M ions form a three-dimensional distorted perovskite-like s...

The TA2 phonon dispersion curves of Ni-Mn-Ga alloys with different compositions which transform to different martensitic structures have been measured over a broad temperature range covering both paramagnetic and ferromagnetic phases. The branches show an anomaly (dip) at a wave number that depends on the particular martensitic structure, and there is softening of these anomalous phonons with d...

The bioaccumulations of metals Cu, Cd, Ni, Cr, Co, Mn, Zn and Fe were measured in bivalves, Cerastoderma glucaum, and four species of fishes including Alburnus chalcoides, Liza aurata, Rutilus frisii and Sander lucioperca from various trophic levels of the Caspian food web. The concentrations of Cd, Cr, Co and Ni in most samples of fish were below the detection limits; while the concentrations ...

We report results of ab-initio calculations of the ferromagnetic Heusler alloy Ni-Mn-Ga. Particular emphasis is placed on the stability of the low temperature tetragonal structure with c/a = 0.94. This structure cannot be derived from the parent L21 structure by a simple homogeneous strain associated with the soft elastic constant C ′. In order to stabilise the tetragonal phase, one has to take...

Binary and ternary separations of heavy metals, e.g. Zn–Bi, Mn–Pb, Cd–Pb, Mn–Bi–Mo, and Cr–Pb–Bi on columns of titanium(IV) tungstosilicate and Zn–Ni, Mo–Pb, Hg–Pb, Zn–Cr–Bi, and Zn–Ni–Bi on titanium(IV) tungstophosphate, have been demonstrated. The adsorption and elution of important metal ions such as Mo, Al, and As on titanium(IV) tungstosilicate and Hg, Fe, and Cr on titanium(IV) tungstopho...

Cobalt hydrate and doped binary Co0.9M0.1OOH (M = Ni, Mn, Fe) nanorings of 100-300 nm were fabricated in solution through a facile ambient oxidation method. A transformation from Co0.9Ni0.1(OH)2 nanodiscs to hollow Co0.9Ni0.1OOH nanorings was observed with prolonged reaction time. Core-shell nanodiscs have elemental segregation with a Co(OH)2 core and Ni(OH)2 shell. Co0.9Ni0.1OOH nanorings disp...

introduction the shahrestanak mn deposit is located in southern qom province, 12 km southwest of the city of kahak. based on geological-structural divisions of iran, the deposit belongs to central volcanic belt or urumieh-dokhtar zone. the venarch deposit is one the most important known manganese deposits in iran. the sharestanak and venarch deposits are spatially and temporally related to each...