Nanoporous alumina membranes exhibit high pore densities, well-controlled and uniform pore sizes, as well as straight pores. Owing to these unusual properties, nanoporous alumina membranes are currently being considered for use in implantable sensor membranes and water purification membranes. Atomic layer deposition is a thin-film growth process that may be used to modify the pore size in a nan...

Graphene and other two-dimensional materials offer a new approach to controlling mass transport at the nanoscale. These materials can sustain nanoscale pores in their rigid lattices and due to their minimum possible material thickness, high mechanical strength and chemical robustness, they could be used to address persistent challenges in membrane separations. Here we discuss theoretical and ex...

Porous graphene (PG) forms a class of graphene-related materials with nanoporous architectures. Their unique atomic arrangements present interconnected networks high surface area and pore volume. Some remarkable properties PG, such as mechanical strength good thermal stability, have been widely studied. However, their electrical conductivity, most importantly, charge transport mechanism are sti...

By taking advantage of cellulose, graphene oxide (GO), and the process for crosslinking using epichlorohydrin (ECH), we propose a simple and novel method to prepare GO/cellulose hydrogel with good potential to adsorb metal ions. GO nanosheets containing carboxyl and hydroxyl groups were introduced into the surface of the cellulose hydrogel with retention of the gel structure and its nanoporous ...

Nanoporous single-layer graphene is promising as an ideal membrane because of its extreme thinness, chemical resistance, and mechanical strength, provided that selective nanopores are successfully incorporated. However, screening understanding the transport characteristics large number possible pores in limited by high computational requirements molecular dynamics (MD) simulations difficulty ex...

Graphyne sheet exhibits promising potential for nanoscale desalination to achieve both high water permeability and salt rejection rate. Extensive molecular dynamics simulations on pore-size effects suggest that γ-graphyne-4, with 4 acetylene bonds between two adjacent phenyl rings, has the best performance with 100% salt rejection and an unprecedented water permeability, to our knowledge, of ~1...

We demonstrate the operation of a graphene-passivated on-chip porous silicon material as a high rate lithium battery anode with over 50 X power density, and 100 X energy density improvement compared to identically prepared on-chip supercapacitors. We demonstrate this Faradaic storage behavior to occur at fast charging rates (1-10 mA cm(-2)) where lithium locally intercalates into the nanoporous...

Water transport through a two-dimensional nanoporous membrane has attracted increasing attention in recent years thanks to great demands in water purification and desalination applications. However, few studies have been reported on the microscopic mechanisms of water transport through structured nanopores, especially at the atomistic scale. Here we investigate the microstructure of water flow ...

Complex electrolyte diffusion through the stacked graphene nanosheets limits their electrochemical performance. As a potential solution, this study explored of nitrogen-doped quantum dots (NGQDs) to induce 3D porous orientation holey oxide (hGO) nanosheets. The sizes NGQDs and antisolvent for phase separation assisted assembly were optimized achieve nanoporous network. This nano-network serves ...

isotherm equation is one of the important scientific bases for adsorbent selection. there are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. it is interesting to introduce a general isotherm, which considers different chemisorption geometries of an adsorbate on nanoporous surfaces. in this study, an isotherm for non-dissoci...