A number of 1,4-bis(phenylethynyl)benzene derivatives (BPEBs) and their analogues with different numbers of side-substitute fluorine atoms on benzene rings, and alkyl chains, ethoxyl groups, fluorine atoms and trifluoromethyl groups as the end groups have been synthesized. The effects of the different substituents on their properties such as thermal behavior of melting point and clearing point,...

Thin smectic liquid crystal films with competing boundary conditions (planar and homeotropic at opposing surfaces) form well-known striated structures known as “oily streaks”, which are a series of hemicylindrical caps that run perpendicular to the easy axis of the planar substrate. The streaks vanish on heating into the nematic phase, where the film becomes uniform and exhibits hybrid alignmen...

An energy-based, phase field model is developed for the coupling of two incompressible, immiscible complex fluid phases, in particular a nematic liquid crystal phase in a viscous fluid phase. The model consists of a system of coupled nonlinear partial differential equations for conservation of mass and momentum, phase transport, and interfacial boundary conditions. An efficient and easy-to-impl...

A new theory of hydrodynamics of uniaxial nematic liquid crystal films in the presence of defects is developed. A gauge field incorporating screening is introduced, resulting in the static elastic free energy having the form of a two-dimensional Abelian-Higgs model. Hydrodynamic equations are derived via the standard methods of de Groot and Mazur. By working in the vicinity of the Bogomol’nyi e...

In this work we investigate the interplay between flow and boundary condition effects on the orientation field of a thermotropic nematic liquid crystal under flow and confinement in a microfluidic device. Two types of experiments were performed using synchrotron small-angle X-ray-scattering (SAXS). In the first, a nematic liquid crystal flows through a square-channel cross section at varying fl...

Microorganisms often encounter anisotropy, for example in mucus and biofilms. We study how anisotropy and elasticity of the ambient fluid affects the speed of a swimming microorganism with a prescribed stroke. Motivated by recent experiments on swimming bacteria in anisotropic environments, we extend a classical model for swimming microorganisms, the Taylor swimming sheet, actuated by small-amp...

We use double-emulsion drops to experimentally investigate the defect structures of spherical shells of nematic liquid crystals. We uncover a rich scenario of coexisting defect structures dictated by the unavoidable finite thickness of even the thinnest shell and by the thickness variation around the sphere. These structures are characterized by a varying number of disclination lines and pairs ...

The first photoresponsive cholesteric liquid crystal comprising a photoisomerizable helical naphthopyran derivative dopant and a nematic liquid crystal is reported. An unprecedented helical twisting power switching ratio of over 90% allowed us to demonstrate multi-cycle rotational motion of micro-objects by UV light irradiation.

A key liquid crystalline property for electro-optic applications is the Frederiks threshold electric field. There has been recent experimental interest in liquid crystal-based colloidal suspensions in which the colloidal nanoparticles both possess a permanent electric polarization and provide strong director anchoring on the particle surface. Such suspensions are sometimes known as Filled Liqui...