Polarization measurements in the Raman spectra of molten sodium nitrite have shown that the reorientational line widths of the vt and v2 bands (both of the A1 symmetry type) of N 0 2 are different. Possible reasons are discussed. Also, the line widths of N 0 2 for various molten nitrites are found to depend on R " 4 , the cloasest approach distance in the melt, and on Z, the cation charge numbe...

The unique opto-electronic properties coupled with small surface of silver nanoparticles have opened the door for their use in sensing applications. Silver are extensively used identification various health and environmentally hazardous pollutants such as heavy metal ions other harmful organic chemicals extremely low detection limits. In recent years, toxicity has further been reduced using gre...

background: the assessment of altered nitric oxide (no) availability is of potentially important diagnostic and prognostic significance. the present study is aimed to investigate the effect of l-arginine (as a natural no donor) supplementation on no metabolite in a rabbit model of hypercholesterolemia to find a reliable marker for endothelial no production. methods: white male rabbits (n = 30) ...

The electrochemical corrosion behaviour of mild steel embedded in concrete, and partially immersed in 0.2M H2SO4, was studied in this investigation at ambient temperature by potential monitoring technique. The experimental work was performed with a digital multimeter and a Cu/CuSO4 electrode (CSE) as the reference electrode. Extracts of carica papaya leaves and sodium nitrite (NaNO2) in differe...

A very simple, sensitive, fairly selective and rapid spectrophotometric method for the determination of trace amounts of nitrite has been described. This method is based on the diazotized intramolecular coupling of electrophilic diazonium cation with the phenolic group of 4-amino-5-hydroxynaphthalene-2,7-disulphonic acid monosodium salt (AHNDMS) in a phosphate buffer solution of pH 7.5. The cyc...

One of the ultimate goals of ion chromatography is to determine both anions and cations found in samples with a single chromatographic run. In the present article, recent progress in ion-exclusion/ion-exchange chromatography for the simultaneous determinations of inorganic anions and cations are reviewed. Firstly, the principle and the control for the simultaneous separation and detection of ...

Formate is a major metabolite in the anaerobic fermentation of glucose by many enterobacteria. It is translocated across cellular membranes by the pentameric ion channel/transporter FocA that, together with the nitrite channel NirC, forms the formate/nitrite transporter (FNT) family of membrane transport proteins. Here we have carried out an electrophysiological analysis of FocA from Salmonella...

An Arthrobacter protophormiae strain RKJ100, isolated by selective enrichment, was capable of utilizing o-nitrobenzoate (ONB(+)) as the sole carbon, nitrogen, and energy source. The degradation of ONB proceeds through an oxygen insensitive reductive route as shown by the release of ammonia in the culture medium aerobically rather than nitrite ions. Thin-layer chromatography, gas chromatography,...