This study presents the synthesis of polyvinyl acetate (PVAc) by solution polymerization and its partial hydrolysis to polyvinyl alcohol (PVA) using alkaline alcoholysis. The influence of the molar ratio of hydrolysis catalyst (NaOH) to PVAc and the time and temperature of the saponification reaction on the degree of hydrolysis and molecular weight of the PVA were investigated using response su...

The rate of ammonia synthesis over a nanoparticle ruthenium catalyst can be calculated directly on the basis of a quantum chemical treatment of the problem using density functional theory. We compared the results to measured rates over a ruthenium catalyst supported on magnesium aluminum spinel. When the size distribution of ruthenium particles measured by transmission electron microscopy was u...

in the present study, tin-promoted pd/mwnts nanocatalystwas synthesized via polyol technique for application in hydrogenation of high-concentrated acetylene feedstocks. tem images showed a restricted distribution of nanoparticles in the range of 3-5 nm. the results indicated that nanoparticles sizes were resistant to further catalyst deactivation. xrd patterns signified alloying between pd and ...

There is given a graph, that models a communication network of a multi-processor system, and there are tokens (jobs) allocated to nodes of the graph. The task is to distribute the tokens evenly, subject to the constraint that they may be moved only along the edges of the graph. The cost of a distribution strategy is measured as the total number of operations of moving a token along an edge. An ...

Support vector machine (SVM) has been one of the most popular learning algorithms, with the central idea of maximizing the minimum margin, i.e., the smallest distance from the instances to the classification boundary. Recent theoretical results, however, disclosed that maximizing the minimum margin does not necessarily lead to better generalization performances, and instead, the margin distribu...

Maximum margin clustering (MMC), which borrows the large margin heuristic from support vector machine (SVM), has achieved more accurate results than traditional clustering methods. The intuition is that, for a good clustering, when labels are assigned to different clusters, SVM can achieve a large minimum margin on this data. Recent studies, however, disclosed that maximizing the minimum margin...

Optimal distribution substation placement is one of the major components of optimal distribution system planning projects. In this paper optimal substation placement problem is solved using Imperialist Competitive Algorithm (ICA) as a new developed heuristic optimization algorithm. This procedure gives the optimal size, site and installation time of medium voltage substation, using their relate...

This study presents a novel anodic PdAu/VGCNF catalyst for electro-oxidation in a glycerol fuel cell. The reaction conditions are critical issues affecting the glycerol electro-oxidation performance. This study presents the effects of catalyst loading, temperature, and electrolyte concentration. The glycerol oxidation performance of the PdAu/VGCNF catalyst on the anode side is tested via cyclic...

The formation of carbonaceous deposits (coke) in zeolite pores during catalysis leads to temporary deactivation of catalyst, necessitating regeneration steps, affecting throughput, and resulting in partial permanent loss of catalytic efficiency. Yet, even to date, the coke molecule distribution is quite challenging to study with high spatial resolution from surface to bulk of the catalyst parti...