This paper describes an automatic method for the optimization of reaction rate constants of reduced reaction mechanisms. The optimization technique is based on a genetic algorithm that aims at finding new reaction rate coefficients that minimize the error introduced by the preceding reduction process. The error is defined by an objective function that covers regions of interest where the reduce...

Today, there is a high number of injuries and various wastes and debris produced during natural and unnatural events. This study aims to investigate the reverse logistics planning problem in the response and reaction phases as well as improvement and reconstruction in earthquake conditions by using a real case study. Regarding the high complexity of this type of optimization problem, a multi-ob...

a new method of optimization on linear parabolic solar collectors using exergy analysis is presented. a comprehensive mathematical modeling of thermal and optical performance is simulated and geometrical and thermodynamic parameters were assumed as optimization variables. by applying a derived expression for exergy efficiency, exergy losses were generated and the optimum design and operating co...

The ring-opening polymerization of δ-valerolactone catalyzed by a thermophilic esterase from the archaeon Archaeoglobus fulgidus was successfully conducted in organic solvents. The effects of enzyme concentration, temperature, reaction time and reaction medium on monomer conversion and product molecular weight were systematically evaluated. Through the optimization of reaction conditions, poly(...

In this study, the optimum conditions (pH, amount of protein, substrate concentration, incubation time) of a cytochrome P450 dependent enzyme, coumarin 7-hydroxylase (COH), activity were determined in microsomal fractions of mouse liver and brain. It’s indicated that different reaction conditions are required for this enzyme activity in mouse liver and brain microsomes. The results obtained, re...

The scope, generality, and mechanism of the Dess-Martin periodinane-mediated cyclization reaction of unsaturated anilides discovered during the total synthesis of the CP-molecules (phomoidrides A and B) are delineated. A plethora of heterocyclic compounds are accessible by employing gamma,delta-unsaturated amides (derived from anilines and carboxylic acids), urethanes, or ureas (derived from is...

An aqueous solution of boric acid, as an efficient and green catalytic system, was efficiently utilized four-component cascade reaction of aryl aldehydes, dimedone, β-ketoesters and ammonium acetate to give hexahydroquinolines. By the reaction of boric acid with water, H+ was generated and efficiently catalyzed the reaction under mild and green condition. Also, optimization of the reaction cond...