Bis(tri-'butyI-phosphine)gold(I) Tetrafluoroborate Alexander Sladek, Hubert Schmidbaur* Anorganisch-Chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-85747 Garching Z. Naturforsch. 50b, 859-863 (1995); received November 11, 1994 (Phosphine)gold(I) Complexes, [(Phosphine)gold(I)]ammonium Cations, Auriophilicity, G old-G old Contacts The reaction of tris[(tri-'butyl-...

To provide further insight into electronic and steric factors and to quantify their relative importance, we studied in detail the migratory CO insertion step for RhMe(CO)I2(L–L) systems (L–L = dppms (PPh2CH2P(S)Ph2) or dppe (PPh2CH2CH2PPh2)), Monsanto catalysts and some electronically unsymmetrical diphosphine model systems. The difference in the reaction rates of dppms and dppe has a clear ele...

A comparison between phosphine boranes and sulfides in their catalytic asymmetric deprotonation using organolithiums and sub-stoichiometric amounts of (-)-sparteine has revealed superior catalytic efficiency in the phosphine sulfide deprotonation.

Two potentially tripodal ligands, tris(1-phenyl-1H-1,2,3-triazol-4-yl)phosphine oxide (OP(1,2,3Tz1?Ph)3) and tris(1-benzyl-1H-1,2,3-triazol-4-yl)phosphine (OP(1,2,3Tz1?benz)3), were used in reactions with [Re(CO)5Br] (NEt4)2[Tc(CO)3Cl3]. While the formation of rhenium complexes bidentate tridentate coordinated phosphine oxides was observed, for technetium only cationic OP(1,2,3Tz1?R) ligands is...

Phosphine derivatives of alkylidyne tricobalt carbonyl clusters have been tested as catalysts/catalyst precursors in intermolecular and (asymmetric) intramolecular Pauson-Khand reactions. A number of new phosphine derivatives of the tricobalt alkylidyne clusters [Co3(micro3-CR)(CO)9] (R = H, CO2Et) were prepared and characterised. The clusters [Co3(micro3-CR)(CO)9-x(PR'3)x] (PR'3 = achiral or c...

Z. Naturforsch. 52 b, 217-220 (1997); received December 16, 1996 Gold(I) Coordination, Tris(phenylthiomethyl)phosphine, Ambidentate P/S3-Ligand The reaction of tris(phenylthiomethyl)phosphine with equimolecular amounts of [AuPPh3]+[BF4]~ affords the complex (tris(phenylthiomethyl)phosphine)(triphenylphosphine)-gold(I) tetrafluoroborate 1 in good yield. The X-ray diffraction analysis of this pro...

The efficacy of phosphine has been established for numerous major stored product insects. However, data related to the evaluation effect on Tenebrio molitor L and Alphitobius diaperinus Panzer are limited. present study aims evaluate susceptibility these species by using following protocols: (a) all life stages were exposed 3 days different concentrations phosphine, (b) adults 3000 ppm until in...

Herein we present an unusual phosphine-free method to fabricate water soluble CdSeS nanocrystals in cubic structure. In this method, glycerin was used as a stabilizing agent replacing tri-n-octylphosphine oxide (TOPO). Water solution of Na2SeO3 in polyethylene glycol was utilized as Se source. 3-Mercaptopropionic acid (MPA) provides S source. The phosphine-free Se and S sources were found to be...

Cell-surface glycans are attractive targets for molecule imaging due to their reflection of cellular processes associated with development and disease progression. In this paper, we describe the design, synthesis, and biological application of a new phosphine probe for real-time imaging of cell-surface glycans using bioluminescence. To accomplish this goal, we took advantage of the bioorthogona...