Chloride and carbonates have the potential to impact pathway, kinetics, and efficiency of oxidation reactions, both as radical scavengers and as metal complexing agents. Traditionally, it is assumed that they have an overall negative impact on the activated persulfate performance. This study investigated the influence of carbonates and chloride on the reactivity of persulfate for three differen...

Poly- and perfluoroalkyl substances (PFASs) have been detected in an increasing number of water supplies. In many instances, the contamination is associated with the use of PFAS-containing aqueous film-forming foams (AFFF) in firefighting activities. To investigate the potential for remediating AFFF contamination in groundwater with heat-activated persulfate, PFAS oxidation and the generation o...

This study was investigated the efficiency of activated persulfate and ‎in-vessel composting for removal of total petroleum hydrocarbons. ‎Remediation by activated persulfate with ferrous sulfate as pre-treatment was done at batch system. In the chemical oxidation, various variables including persulfate concentrations (10-3000 mg/g as waste), ...

Heat-activated persulfate was tested for destruction of polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) in the laboratory. Combined technology of in situ chemical oxidation (ISCO) and in situ thermal remediation (ISTR) using heat-activated persulfate can be applied for destruction of the PCDD/Fs polluted soil and the PCDD/Fs containing fly ash from incineration process. To explore the treata...

The impact of chemical on the native microbial population during in situ chemical oxidation (ISCO) is not well understood. As a result, some concerns exist within the remediation community as to the potential of negative impacts ISCO may have on bioremediation processes, especially its impact on down-gradient plume control via bioremediation and its impact on subsequent natural attenuation proc...

ENVIRONMENTAL APPLICATIONS OF PERSULFATE: REMEDIATION CONTAMINATED GROUNDWATER AND SOILS. Environmental remediation represents a major technological challenge due to the complexity of environmental matrices and high treatment cost. In recent years, in situ chemical oxidation technologies (ISCO) have shown good cost/benefit ratio, which as favored their use degradation several relevant pollutant...

Zero-valent iron [Fe(0)]-biochar composites, namely, Fe(0)-included biochar and biochar-coated Fe(0), were synthesized their catalytic performance in the activation of persulfate for phenol degradation water was evaluated. In presence Fe(0)-biochar biochar-persulfate Fe(0)-persulfate systems showed higher removal than a system by 11.6% 20.7%, respectively. The difference between Fe(0) because h...

Superabsorbent polymer was prepared by graft polymerization of acrylic acid onto the chain of cellulose from flax shive by using potassium persulfate (KPS) as an initiator and N,N-methylenebisacrylamide (MBA) as a crosslinker under microwave irradiation. SEM photographs were also studied for more information about the shive, cellulose from shive, and the superabsorbent polymer. The structure of...

Silicon carbide (SiC) is a wide bandgap third-generation semiconductor well suited for harsh environment power electronics, micro and nano electromechanical systems, emerging quantum technology by serving as hosts states via defect centers. The chemical inertness of SiC limits viable etching techniques to plasma-based reactive ion methods; however, these could have significant undesirable effec...