In recent years, parametric relationships between interatomic potential energy functions have been developed in the realm of molecular chemistry and condensed matter physics. However, no parametric relationships have been developed so far among intra-atomic potentials. As an extension of previous works into the realm of intra-atomic potentials, we herein consider the possibility that hadronic p...

A new instanton solution is found in the quantum-mechanical double-well potential with a four-fermion term. The solution has finite action, S = −m3 3λ − ( mA 4 √ 2λ + g 261m 8960 ) ǫξiξjξkξl, where A is a bosonic collective coordinate, ξi, i = 1, ..., 4 are fermionic collective coordinates and g,m and λ are coupling constants. We explain why in general the instanton action can depend on collect...

We report second and third virial coefficients for the system CO2-H2O, calculated via cluster integrals using quantitative molecular models taken from the literature. Considered models include (1) fits to highly accurate ab initio calculations of the potential energy surfaces, and (2) semi-empirical Gaussian Charge Polarizable Models (GCPM). Three-body effects are found to be essential for obta...

In this introductory exploration of the title theme, we treat a positron as a light nucleus and work within the quasimolecule approximation to obtain, for the first time, adiabatic potential energy curves for its scattering by the He atom. We then show that different elastic and inelastic processes that contribute to the total scattering cross section can be rationalized in molecular terms as d...

Electronic Structure Theory describes the motions of electrons in atoms or molecules. Generally this is done in the context of the Born-Oppenheimer Approximation, which says that electrons are so much lighter (and therefore faster) than nuclei that they will find their optimal distribution for any given nuclear configuration. The electronic energy at each nuclear configuration is the potential ...

for the quintet state of the O2„ 3 g − ...–O2„ 3 g − ... dimer Massimiliano Bartolomei, Estela Carmona-Novillo, Marta I. Hernández, José Campos-Martínez, and Ramón Hernandez-Lamoneda Instituto de Matemáticas y Física Fundamental, Consejo Superior de Investigaciones Científicas, Serrano 123, 28006 Madrid, Spain Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, 62210...

The laser excited, jet-cooled Ã2A′′ 2 − X̃2E′′ 1 electronic spectrum of the cyclopentadienyl radical yields detailed information about the vibronic structure of both its à and X̃ states. A straight-forward assignment of the à vibronic structure is presented. The X̃ state vibronic structure reveals a comprehensive picture of the Jahn-Teller distortion of its potential energy surface. The molecular ...

Ro-vibrational calculations on a recent ab initio potential energy surface for H: (W. Meyer et al., J. Chem. Phys. 84, 891 (1986)) are presented for the isotopomers H,_.D: (n = 0, 1, 2, 3). These calculations employ refinements recently developed for nuclear motion calculations and are thus of very high accuracy. The rotational levels with .I G 4 are fitted to standard vibrationrotation Hamilto...

abstract background: simultaneous occurrence of psychiatric disorders and substance abuse isorders have widespread effects and are associated with worse prognosis. addicts should be treated in accordance with the requirements of each of these people. this study aimed at investigating the simple and multiple relationships between morningness/eveningness, anxiety sensitivity and addiction potenti...