Six homochiral coordination polymers 1-6 based on an enantiopure elongated and bent bipyridine ligand were synthesized and characterized by single-crystal X-ray diffraction studies. The framework structures of all six compounds were built up from similar 1D polymeric chains composed of 46-membered metallomacrocycles. Four distinct packing patterns were observed for this family of coordination p...

We present a sensitive 3 upper limit of 1.1% for the HNC/HCN abundance ratio in comet 73P/SchwassmannWachmann (fragment B), obtained on 2006May 10Y11, using Caltech Submillimeter Observatory (CSO). This limit is a factor of 7 lower than the values measured previously in moderately active comets at 1 AU from the Sun. Comet 73P/Schwassmann-Wachmann was depleted in most volatile species, except of...

The interface layer between ocean and atmosphere is only a couple of micrometers thick but plays a critical role in climate relevant processes, including the air-sea exchange of gas and heat and the emission of primary organic aerosols (POA). Recent findings suggest that low-level cloud formation above the Arctic Ocean may be linked to organic polymers produced by marine microorganisms. Sea ice...

In this work, a pressure-sensitive adhesive (PSA) was used as the model substance for secondary stickies. The dissolved and colloidal substances (DCS) prepared from bleached chemithermomechanical pulp (BCTMP) and the effects of pectinase treatment on the stickies deposition were evaluated. The results showed that the addition of DCS lowered the efficiency of cationic polymers and aggravated the...

Water-soluble hydrophobically associating polymers are examined with particular emphasis on their rheology for oilfield applications. The incorporation of a small amount (less than 1 mol%) of hydrophobic groups into the polymer backbone of a water-soluble polymer dramatically alters the rheological properties of the resulting material. Associating polymers have potential for use in mobility con...