Laser Raman spectra, UV-visible spectra, and photo-catalytic activity measurements are described which show that supported MoO,iTiOr catalysts prepared by impregnation possess a layer of surface molybdate species coordinated to the titania support. The saturation coverage of this surface molybdate monolayer corresponds to a surface density of ca. 4 x lOI MO atoms per cm2 of TiO*. The properties...

Several biotinyl estradiol derivatives have been prepared by coupling estradiol 7 alpha-carboxylic acid to biotin via different linear linkers. All these compounds exhibit a high affinity for the estrogen receptor as determined by competitive binding assays against [3H]estradiol. These compounds also displaced the dye 4-hydroxyazobenzene-2'-carboxylic acid from the biotin-binding sites of avidi...

In this research, mesoporous silica was applied as the host of corrosion inhibitor (molybdate). The loaded mesoporous silica was dispersed in an epoxy matrix. The composite was then coated on the mild steel plate. Results showed that the corrosion resistance of the scratched epoxy/mesoporous silica loaded by molybdate was better than the one without molybdate or neat epoxy. On the other hand, E...

To fulfill the demands of more bandwidth in 5G and 6G communication technology, new dielectric substrates that can be co-fired into packages devices have low loss improved thermal conductivity are desired. The motivation for this study is to design composites with (tan δ) high (κ), while still limiting electrical conductivity, microwave applications involving power frequency. This work describe...

Several methods have been proposed for obtaining highresolution NMR spectra of half-integer spin quadrupolar nuclei (I ) /2, /2, etc.) in powdered solids. The double-rotation (DOR), dynamic-angle spinning (DAS), multiple-quantum magic-angle spinning (MQMAS), and satellite-transition magic-angle spinning (STMAS) techniques1 have attracted great interest owing to the importance of the nuclides 11...

We have previously reported that molybdate-stabilized cytosol prepared from 32P-labeled L-cells contains two phosphoproteins (a 90-92- and a 98-100-kDa protein) that elute from an affinity resin of deoxycorticosterone-derivatized agarose in a manner consistent with the predicted behavior of the glucocorticoid receptor (Housley, P. R., and Pratt, W. B. (1983) J. Biol. Chem. 258, 4630-4635). In t...

Nucleic acid extracted from environmental samples is an important analyte in instrumental analysis. With respect to the phenomenon which sodium tungstate promotes methane production anaerobic digestion, analyses of microbial community using RNA were conducted; however, we noticed that only concentration measured by absorbance measurement (NanoDrop) was remarkably high. Therefore, this study, DN...

Efficient one-pot catalytic synthesis of (+)-nootkatone was performed from (+)-valencene using only hydrogen peroxide and amphiphilic molybdate ions. The process required no solvent and proceeded in three cascade reactions: (i) singlet oxygenation of valencene according to the ene reaction; (ii) Schenck rearrangement of one hydroperoxide into the secondary β-hydroperoxide; and (iii) dehydration...