In situations involving large potentials or surface charges, the Poisson-Boltzman (PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This has been widely recognized by the electrochemistry community, leading to the development of various alternative models resulting in different sets "modified PB equations," which have had at least qualitative success in...

The electrostatic attraction between electrons and nuclei is a fundamental force in electrochemistry. This drives the interaction nuclei, providing potential for redox reactions. As result, it basis of chemistry. In recent years, organic electrochemistry has made significant progress oxidative hydrogen evolution coupling sacrificial anode electroreduction, thanks to its efficient environmentall...

Electrochemistry is promising to study interfacial electron transfers and redox reactions, but its lack of access molecular structural information limits understanding on complicated systems. Complementary optical spectroscopic measurements in situ become necessary visualize the electrochemical processes, providing electronic identification reactants products. Recent advancement instrumentation...

Noble metal nanoparticles with plasmon resonance features have been widely applied in electrocatalysis and photo-electrochemistry owing to their unique physical, optical, catalytic properties. As heterogeneity of nanostructures has considerable influence on activities, investigation electrochemical process a single nano-catalyst is necessary eliminate bulk effect averaged results. Dark-field mi...

The thermodynamics of ferric and ferrous haem affinity of a de novo designed four-alpha-helix bundle protein and the associated haem electrochemistry is described.

Electrochemistry and adlayer structure of trinitrotoluene (TNT) on an Au(111) electrode were investigated using cyclic voltammetry and in situ electrochemical scanning tunneling microscopy (ECSTM).

Four rhenium(I) chromophores attached to a dirhodium(n) core form a new hexametallic light-harvesting assembly as characterised by X-ray crystallography, UV-vis spectroscopy and electrochemistry.