Oxidation of thioglycolic acid (HSCH2CO2H, TGA) by [IrCl6] 2 (Ir()) in aqueous solution at 25 C is highly susceptible to trace metal-ion catalysis. This catalysis can be effectively suppressed by bathophenanthrolinedisulfonate (bathophen), allowing the direct oxidation to be studied. Although the corresponding disulfide is produced quantitatively in the absence of bathophen, a mixture of the ...

Colloidal CdSe quantum dots (QDs) of different sizes, prepared by a solvothermal route, have been employed as sensitizers of nanostructured TiO(2) electrode based solar cells. Three different bifunctional linker molecules have been used to attach colloidal QDs to the TiO(2) surface: mercaptopropionic acid (MPA), thioglycolic acid (TGA), and cysteine. The linker molecule plays a determinant role...

Serum, taken from rats under ether anesthesia after injection of hypertonic saline, contained antidiuretic activity in a concentration equivalent to 1 to 3 millipressor units of pitressin per ml. The active material was retained by a collodion ultrafilter and, on electrophoretic analysis, moved with the beta globulins. Dialysis against 0.2 N acetic acid appeared to dissociate the complex. The a...

Synthesis of 2-[2-(2,6-dichlorophenyl)amino]phenylmethyl-3-[4-(2-substitutedphenyl-4-oxo-thiazolidinyl)aryl]-6-bromo quinazolin-4(3H)ones VIa-j have been achieved from the starting material 2-[(2,6-dichlorophenyl)amino] phenylacetic acid I to benzoxazine III, Further reaction with p-phenylindiamine and substituted aromatic aldehyde gave 2-[2-(2,6-dichlorophenyl)amino]phenyl methyl-3-(4-aminoary...

Synthesis of 2-[2-(2,6-dichlorophenyl)amino]phenylmethyl-3-[4-(2-substitutedphenyl-4-oxo-thiazolidinyl)aryl]-6-bromo quinazolin-4(3H)ones VIa-j have been achieved from the starting material 2-[(2,6-dichlorophenyl)amino] phenylacetic acid I to benzoxazine III, Further reaction with p-phenylindiamine and substituted aromatic aldehyde gave 2-[2-(2,6-dichlorophenyl)amino]phenyl methyl-3-(4-aminoary...