5.3. Xenobiotic Trace Metals and Materials 4804 5.3.1. Toxicology of Heavy Metals 4804 5.3.2. Nanoparticle Applications 4810 5.4. Environmental Metal Speciation 4812 5.4.1. Bacteria 4812 5.4.2. Aquatic Organisms 4812 6. Mass Spectrometry Imaging Techniques 4813 6.1. Secondary Ion Mass Spectrometry (SIMS) 4813 6.1.1. Metal Ion Distribution in Chromosomes 4813 6.1.2. Subcellular Distribution of M...

We combine ab initio density functional theory with transport calculations to provide a microscopic basis for distinguishing between good and poor metal contacts to nanotubes. Comparing Ti and Pd as examples of different contact metals, we trace back the observed superiority of Pd to the nature of the metal-nanotube hybridization. Based on large scale Landauer transport calculations, we suggest...

Concentrations of 33 metal elements were determined by ICP-MS (Inductively Coupled Plasma Mass Spectrometry) analysis for 24 cloud water samples (corresponding to 10 cloud events) collected at the puy de Dôme station. Clouds present contrasted chemical composition with mainly marine and continental characteristics; for some cloud events, a further anthropogenic source can be superimposed on the...

Historic lead and zinc (Pb-Zn) mining in southeast Missouri’s ―Old Lead Belt‖ has left large chat piles dominating the landscape where prior to 1972 mining was the major industry of the region. As a result of variable beneficiation methods over the history of mining activity, these piles remain with large quantities of unrecovered Pb and Zn and to a lesser extent cadmium (Cd). Quantifying the r...

Evidences supporting the introduction of metallic elements in several biological processes are rapidly accumulating. Likewise, many drugs possess modified toxicological and pharmacological properties when in the form of metal complexes. In order to ascertain the role of various essential and trace element complexation on the antibacterial activity of various cephalosporins, the synergistic or a...

an ex-situ experiment to assess the metal extractive potential of fourteen agriculture plants (vigna unguiculata, gossypium hirsutum, jatropha curcas, etc.) was conducted on magnesite mines which had above permissible levels of cadmium and lead. there was no much difference in the total chlorophyll a and b, carbohydrate and protein contents in the plants grown in the mining soil and adjacent co...

Synchrotron X-ray fluorescence microscopy (SXRF) is a microanalytical technique for the quantitative mapping of elemental distributions. Among currently available imaging modalities, SXRF is the only technique that is compatible with fully hydrated biological samples such as whole cells or tissue sections, while simultaneously offering trace element sensitivity and submicron spatial resolution....

1. Basic Concepts 1.1. Air Pollution 1.2. Criteria and Non-Criteria 1.3. Emissions 2. The Epidemiological Model 3. Toxic Trace Elements from Fossil Fuel Combustion 4. Environmental Behavior of Metal Pollutants 4.1. Atmospheric Aerosol Particles 4.2. Aqueous and Marine Environments 4.3. Accumulation of Heavy Metals in Marine Invertebrates 4.4. Heavy Metal ions in Soils 4.5. Methylation of Heavy ...

The use of multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) for trace metal stable isotope analysis is well established within geochemistry, essentially since the conception of such instruments. The utilization of this high precision technique in medical and life science research has only just begun, however, and the scope of applications is vast, from diagnosis to me...

This article presents a review of the analytical relevance of trace metal speciation analysis, which must be considered in environmental and biophysicochemical systems for reliable and efficient assessment and monitoring of trace metals. Examples are given of methodological approaches used for speciation analysis. An overview of speciation analysis in sediments, aquatic ecosystems and agrosyste...