Radical-based carbonylation reactions of alkyl halides were conducted in a microflow reactor under pressurized carbon monoxide gas. Good to excellent yields of carbonylated products were obtained via radical formylation, carbonylative cyclization and three-component coupling reactions, using tributyltin hydride or TTMSS as a radical mediator.

Trichloroethylene (Tri) continues to be extensively used as an industrial solvent for fats and oils.1) As a xenobiotic metabolized by the microsomal mixed function oxidase system (MFOS) Tri is able to destroy, inhibit and induce microsomal enzymes. Costa et al.2) reported that incubation of hepatic microsomes with NADPH and trichloroethylene resulted in decreased levels of cytochrome P-450, but...

phosphoryl containing ligand tri-n-octylphosphine oxide (topo) in dichloromethane has been used as an extracting agent for tetravalent thorium and trivalent europium ions from their 1 m sodium nitrates. the equilibrium data reveal that both ions are extracted as the complexes at 1:3 metal/ligand ratio. the values of conditional extraction equilibrium constant (kex) show the superior extractive ...

in recent years, zinc oxid nanotubes have attracted much attention. the direct use of , zinc oxidnanotubes modified by sio2 as recoverable catalysts for organic reactions is very rare. the catalystswere characterized by xrd. the average particle size of zno catalysts is 57 nm and there are highdensitydefects on nanotubes surfaces . a simple and efficient method for the imidazol derivativessynth...

As of 1998, electric utility companies burning coal or oil are required to report their annual releases of toxic chemicals to the Toxics Release Inventory (TRI), a national compilation of multimedia (air, water, land) releases of over 600 chemicals and chemical categories designated as toxic by the U.S. Environmental Protection Agency (EPA). TRI reports for 1998 must be filed with EPA by July 1...

Occupational exposure to trichloroethylene (TRI) was studied by analysis of environmental air and urine from 49 workers operating in a special printing house on glass. For the measurement of environmental concentration of TRI (Cenv), the ambient air was sampled using personal passive dosimeters. The activated charcoal was desorbed with carbon disulfide and injected into a gas-cromatograph - mas...

In this paper, we introduce the notions of $(odot, oplus)$-derivations and $(ominus, odot)$-derivations for $MV$-algebras and discuss some related results. We study the connection between these derivations on an $MV$-algebra $A$ and the derivations on its boolean center. We characterize the isotone $(odot, oplus)$-derivations and prove that $(ominus, odot)$-derivations are isotone. Finally we d...

Let $X$ be a Banach space of $dim X > 2$ and $B(X)$ be the space of bounded linear operators on X. If $L : B(X)to B(X)$ be a Lie higher derivation on $B(X)$, then there exists an additive higher derivation $D$ and a linear map $tau : B(X)to FI$ vanishing at commutators $[A, B]$ for all $A, Bin B(X)$ such that $L = D + tau$.

We prove that every 2-local derivation from the algebra Mn(A)(n > 2) into its bimodule Mn(M) is a derivation, where A is a unital Banach algebra and M is a unital A-bimodule such that each Jordan derivation from A into M is an inner derivation, and that every 2-local derivation on a C*-algebra with a faithful traceable representation is a derivation. We also characterize local and 2-local Lie d...

As of 1998, electric utility companies burning coal or oil are required to report their annual releases of toxic chemicals to the Toxics Release Inventory (TRI), a national compilation of multimedia (air, water, land) releases of over 600 chemicals and chemical categories designated as toxic by the U.S. Environmental Protection Agency (EPA). TRI reports for 1998 must be filed with EPA by July 1...