نتایج جستجو برای: tungsten compounds
تعداد نتایج: 237355 فیلتر نتایج به سال:
Heavy metal tungsten alloys have replaced lead and depleted uranium in many munitions applications, due to public perception of these elements as environmentally unsafe. Tungsten materials left in the environment may become bioaccessible as tungstate, which might lead to population exposure through water and soil contamination. Although tungsten had been considered a relatively inert and toxico...
Octahedral tungsten iodide clusters equipped with apical ligands (L) are synthesized to implement substantial photophysical properties. The [W6I8(CF3COO)6]2- cluster reported herein is the first example of a family of ligand substituted [W6I8L6]2- clusters. Such compounds are expected to exhibit a rich photochemistry in which the apical ligands play a crucial role. The versatile solid state and...
Manipulating mammalian cell morphologies using chemical-mechanical polished integrated circuit chips
Tungsten chemical-mechanical polished integrated circuits were used to study the alignment and immobilization of mammalian (Vero) cells. These devices consist of blanket silicon oxide thin films embedded with micro- and nano-meter scale tungsten metal line structures on the surface. The final surfaces are extremely flat and smooth across the entire substrate, with a roughness in the order of na...
A new method for relativistically corrected nuclear magnetic resonance ~NMR! chemical shifts is developed by combining the individual gauge for the localized orbital approach for density functional theory with the normalized elimination of a small component using an effective potential. The new method is used for the calculation of the NMR chemical shifts of Mo and W in various molybdenum and t...
Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limi...
This investigation originated in a report by Dr. Joan Cotterill, one of H.M. medical inspectors of factories, that workers in a Midlands factory making hard cutting tools complained of shortness of breath and that in radiographs of their lungs, some of them showed abnormal shadows. Many of the processes in the factory are trade secrets, but it is known that powdered cobalt metal is used as a bo...
High-resolution X-ray absorption measurements (with an accuracy of +/-0.3 eV) of ZnSO(4) (aq) were performed with ultrafast selected energy X-ray absorption spectroscopy (USEXAS) using a laser-driven tungsten target X-ray source. The results were used to determine the absolute spectral positions of characteristic emission lines. By comparing these positions to those predicted for the line emiss...
An insulated nanotube wire is formed by the binary phase of layered tungsten disulphide and carbon nanotubes (shown in the HRTEM image) generated by the sulphidization of tungsten oxide coated multiwalled carbon nanotubes at 900 °C. Thermogravimetric analysis shows that the tungsten disulphide coat acts as an antioxidant.
Tungsten being a transition element, forms oxide compounds of various oxidation states that enables it to form nanocolloids tungsten dihydrate. Multiple methods have been used in recent years synthesize nano dihydrate, including sol-gel synthesis, electrochemical deposition, hydrothermal synthesis and anodization. However, universally accepted method for this material is not offered. The most a...
In this study the microstructure and mechanical properties of super duplex stainless steel UNS S32750 welding was studied. For this purpose, the method of gas tungsten arc and filler metal AWS ER2594 with a diameter of 4.2 mm was used. In order to investigate the microstructure light microscopy and electron microscopy equipped with backscatter electron diffraction were used. Mechanical properti...
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