نتایج جستجو برای: unsaturated compounds
تعداد نتایج: 241045 فیلتر نتایج به سال:
Molybdenum hexacarbonyl (Mo(CO)6) was used as an efficient catalyst for the chemoselective reduction of the amide functionality in α,β-unsaturated compounds, under hydrosilylation conditions using 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydride source.
A diastereoselective access to β-lactam fused spirocyclic oxindoles and related compounds bearing all carbon spiro centers is described. This N-heterocyclic carbene-catalyzed process employed challenging β,β-disubstituted α,β-unsaturated imines to react with enals.
Elucidating absolute configuration of unsaturated alcohols via enantioselective acylation reactions.
Enantioselective nucleophilic acylation catalysis provides a simple method of determining absolute configuration for unsaturated alcohols. Extension of this technique to natural products and synthetic compounds, as well as current limitations of this approach, are also described.
Carbonyl compounds react with organozinc reagents in the presence of diphenyl phosphite to give the corresponding olefins. A variety of 1,3-dienes and unsaturated esters were obtained in moderate to excellent yields under mild conditions.
Glycals 1 and 2 react with methoxybenzene in the presence of SnCLj forming ^-substituted C-glycosyl compounds 4 and 5 + 6 respectively. Under similar conditions l -Obenzoylor methyl pent-2-enopyranos-4-uloses (7) and (8) react with electron rich aromatic compounds furnishing either C-glycosyl compounds or C-2 aryl substituted products depending on the nature of the aromatic component as well as...
Michael addition of pyrimidine and purine nucleobases to substituted as well as unsubstituted α,β-unsaturated esters efficiently proceeds in the presence of catalytic amount of zinc oxide in ionic liquid 1-butyl-3-methylimidazolium bromide (ZnO/[bmim]Br) under microwave irradiation to afford carboacyclic nucleosides, as biologically important compounds, in good to excellent yields and in short ...
Formation of nitro aliphatic compounds are mainly consisted of direct nitro functionalizing of alkanes and alkenes. Nitro functionalization of alkenes has particular importance in the field of energetic materials due to unsaturated nature and the ability to synthesize a wide range of C-nitro aliphatic compounds. Considering the importance of synthesis of these compounds, the use of nitrile iod...
Triphenylphosphine oxide-catalyzed stereoselective poly- and dibromination of unsaturated compounds.
A novel PPh3O catalyzed bromophosphonium salt-mediated dibromination of α,β-unsaturated esters and β,γ-unsaturated α-ketoesters has been developed. The products were obtained with good to excellent yields and excellent diastereoselectivities. This dibromination reaction is a good complement to the field of dibromination.
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