UV/Vis absorption spectra of ClOOCl isolated in neon matrices were measured in the wavelength range 220-400 nm. The purity of the trapped samples was checked by infrared and UV/Vis matrix spectroscopy as well as low-temperature Raman spectroscopy. At wavelengths below 290 nm, the results agree with the UV spectrum recently published by Pope et al. [J. Phys. Chem. A, 2007, 111, 4322-4332]. Howev...

A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between sigma4-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl]thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the sigma3-P,N2,S-hybrid porphyrin exhibits high aromaticity as an 18pi-electron system in terms of bo...

Six new 2-o-(m- and p-)chlorobenzylthio-6-methyl-5-piperidino-(or morpholino-) methyluracils have been prepared. The structures of these compounds were confirmed by spectroscopic (FT-IR, UV-Vis, (1)H NMR, (13)C NMR, and HMBC) and elemental analyses. Estimation of pharmacotherapeutic potential has been made for synthesized compounds on the basis of prediction of activity spectra for substances (...

Taking a natural triterpenoid as the building block, we have regulated a pyridinium-functionalized methyl glycyrrhetate (C4-MGP) into P-type helices in water primarily driven by hydrophobic forces. By analysing their temperature-dependent CD and UV-Vis spectra, these hierarchical chiral assemblies were found to be formed in a cooperative supramolecular polymerization manner.

The atmospherically highly relevant methylsulfinyl radical CH3(O)S˙ was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S˙ and its D3- and (13)C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.

In this data article, the fluorescence, UV-vis absorption and FTIR spectra data of BSA-AR1/AG50 system were presented, which were used for obtaining the binding characterization (such as binding constant, binding distance, binding site, thermodynamics, and structural stability of protein) between BSA and AR1/AG50.

The azo-azomethine dyes were prepared via condensation reaction of 2,4-dichloro-6-methoxy-1,3,5-triazine with azo couled 2-(2-mercaptophenylimino)methyl)-4-(aryldiazenyl)phenol. The UV–vis spectra indicated positive solvatochromism in synthesized compound are dependent on the substitution, solvent, pH and temperature. Some compounds exhibited antibacterial, antioxidant activities.

A novel covalently linked binuclear phthalocyanine 1 was synthesized by the "double-click" reaction. The UV-vis and fluorescence spectra and electrochemistry revealed that the geometry of 1 is a closed clamshell conformation in which a strong electronic interaction is observed between the two Pc moieties.

This paper presents the microstructure, optical and electrical properties of zinc oxide nanorodlike structures deposed on glass substrate by dip-coating method. The crystalline phases and morphology of 1-D nanostructured materials have been investigated using X-ray diffraction and scanning electron microscopy (SEM) techniques. The UV-VIS-NIR spectra and the electrical properties were also measu...

The phenylboronic acids substituted with an azo group on the ortho-position show a significant change in UV-vis spectra upon sugar binding. A new mechanism for the spectral change of the dyes is proposed based on the formation and cleavage of B-N dative bond between boronic acid group and azo group.