Syntheses of N,N'-phenyltetrazole podands link with aliphatic chains containing oxygen, nitrogen and sulphur atoms, are described. The complexing properties of these compounds towards metal cations (Fe2+, Cu2+, Zn2+, Co2+, Ni2+) were investigated by absorption and infrared spectroscopy. The UV-Vis titrations were performed to estimate the stability constant values of the respective complexes wi...

A series of rhenium complexes with acetylamino- and trifluoroacetylamino-containing 1,10-phenanthroline ligands have been synthesized, characterized and their photophysical and electrochemical properties studied. These complexes were found to show significant UV-vis and emission changes on addition of CN(-), F(-) and AcO(-) anions. Their reactivity towards CN(-), F(-) and AcO(-) anions, was als...

A polyethylenimine (PEI) self-assembled monolayer (SAM) is prepared, capable of complexing silver and copper cations and of anchoring silver nanoparticles, exerting antibacterial activity against Escherichia coli and Staphylococcus aureus. Functionalized glassy surfaces have been fully characterized through spectroscopic techniques (UV-Vis spectroscopy, spectroscopic ellipsometry), atomic force...

Drinking water quality with respect to fluoride, iron, and nitrate content has been carried out in Kamrup district of Assam, India. Forty six different sampling stations were selected for the study. Iron was analyzed by using an atomic absorption spectrometer, Perkin Elmer AA 200, while fluoride was measured by the SPADNS method at 570nm and Nitrate content was measured by the phenol-disulphoni...

nanocrystals of zno were prepared by microwave irradiation using zn (ii) acetate and triethanol amin (tea) as the starting materials and water as solvent. the nanocrystals of zno with hexagonal (wurtzite) structure were characterized by x-ray powder diffraction (xrd), transmission electron microscopy (tem), scanning electron microscopy (sem), uv-vis absorption and ftir spectroscopy techniques.

The photoinduced formation of silver (Ag) clusters and particles in poly(vinyl alcohol) poly(acrylic acid) blend films is described. The photoreduction of the Ag is achieved by subjecting the Ag doped films to 350 nm photons. The formation of Ag clusters and particles is monitored using UV-VIS spectroscopy. Films treated with H2O2 exhibit bleaching of the UV-VIS signals corresponding to Ag clus...

Three derivatives of thieno[3,2-b]thiophene end-capped with phenyl units have been synthesized and characterized by MALDI TOF mass spectroscopy, elemental analysis, UV-vis absorption spectroscopy and thermogravimetric analysis (TGA). All compounds were prepared using Pd-catalyzed Stille or Suzuki coupling reactions. Optical measurements and thermal analysis revealed that these compounds are pro...

the reduction capacity of ammonia while present even at ppm level can be demonstrated by the increased encounter probability between ammonia and methylene blue dye (mb+) incorporated in nanomordenite and na-mor zeolites. the rate of reduction methylene blue dye by ammonia on the surface nanomordenite zeolite is faster than na-mordenite (na-mor) zeolite.because nanomordenite zeolite with high si...

The sonication-driven dispersion of single-walled carbon nanotubes (SWCNTs) in aqueous surfactant solution has been monitored by UV-vis-NIR spectroscopy and scanning electron microscopy. Dispersion of SWCNTs experiments reveal that the maximum concentration of dispersed SWCNTs corresponds to the maximum UV-vis-NIR absorbance of the solution. With higher surfactant concentration the dispersion r...