Water oxidation catalysis constitutes the bottleneck for the development of energy-conversion schemes based on sunlight. To date, state-of-the-art homogeneous water oxidation catalysis is performed efficiently with expensive, toxic and earth-scarce transition metals, but 3d metal-based catalysts are much less established. Here we show that readily available, environmentally benign iron coordina...

A novel series of mixed-valent, heteroleptic transition metal diketonates that can be utilized as prospective single-source precursors for the low-temperature preparation of oxide materials are reported. The first mixed-valent iron β-diketonates with different FeIII/FeII ratios have been synthesized by applying the mixed-ligand approach. Based on nearly quantitative reaction yields and analysis...

The purpose of this study was the investigation of the removal of phenol with nanoparticles zero valent iron and iron powder. The effect of various parameters such as initial concentration, pH, contact time, and dosage of NZVI and Fe powder was examined, and a Central Composite Design (CCD) was then applied to appraisal the effect of these variables. The chemical and physical characteristic...

aims: arsenic contamination of natural water resources has become an important environmental problem in the world. the adsorption method by iron filings adsorbent or zero-valent iron was used. the study aimed to evaluate the efficiency of iron filings in arsenite removal from polluted water and to investigate the effect of magnetic field on the process. materials & methods: this interventional ...

Transition-metal-catalyzed [2+2+2] cycloaddition reactions that use two alkynes and a nitrile is the most straightforward and powerful strategy for the construction of multisubstituted pyridines with high atom efficiency. The iron-catalyzed [2+2+2] cycloaddition to form pyridines remains a great challenge in this field, although significant efforts have been made in various catalytic systems (e...

The reaction of Group 6 metals with SWCNT has the potential to bridge the resistive SWCNT . . . SWCNT junctions by the formation of “Cr(SWCNT)2” complexes analogous to Cr(C6H6)2. This study reports that the formation of such species is very sensitive to oxidation by a residual iron oxide catalyst used for the growth of the SWCNTs and adsorbed/bound oxygen functionality. The reaction of raw HiPc...

To help elucidate the mechanism of dechlorination of chlorinated triazines via metallic iron, terbutylazine (TBA: 2-chloro-4-ethylamino-6-terbutylamino-1,3,5-triazine), deisopropyl atrazine (DIA: 2-amino-4-chloro-6-ethylamino-1,3,5-triazine), and chlorinated dimethoxy triazine (CDMT: 2-chloro-4,6-dimethoxy-1,3,5-triazine) were degraded via zero valent iron under controlled pH conditions. The lo...

A new mechanism for alkane functionalization by iron(III)-peroxide adducts was pro­ posed, and the importance of electrophilic nature of the metal-peroxide adduct with t] 1coordination mode was emphasized. This idea suggests that formation of high-valent ironoxo species occurs most likely when the metal-peroxide intermediate is activated through electronic interaction with both the peripheral o...