We investigate the structure and phase behavior of the Stockmayer fluid in the presence of nonuniform electric fields using molecular simulation. We find that an initially homogeneous vapor phase undergoes a local phase separation in a nonuniform field due to the combined effect of the field gradient and the fluid vapor-liquid equilibrium. This results in a high-density fluid condensing in the ...

The effects of the finite size of a liquid drop undergoing a phase transition are described in terms of the complement, the largest (but mesoscopic) drop representing the liquid in equilibrium with the vapor. Vapor cluster concentrations, pressure, and density from fixed mean density lattice gas (Ising) calculations are explained in terms of the complement generalization of Fisher's model. Acco...

In this study, an evaporation coefficient representing the rate of vapor molecules was calculated in a vapor–gas binary mixture and non-equilibrium system using molecular dynamics simulation. The herein refers to state which net occurs, calculation is composed non-condensable (NC) gas molecules. demonstrated have almost same value as that equilibrium state. number density NC around gas–liquid i...

Laboratory chambers, invaluable in atmospheric chemistry and aerosol formation studies, are subject to particle and vapor wall deposition, processes that need to be accounted for in order to accurately determine secondary organic aerosol (SOA) mass yields. Although particle wall deposition is reasonably well understood and usually accounted for, vapor wall deposition is less so. The effects of ...

Packed distillation and absorption columns are often modeled using equilibrium stages. However, determination of the packing height that corresponds to an equilibrium stage is not easy. For binary systems HETP values can be used, but these are not applicable to multicomponent systems because mass transfer rates of different components deviate from each other. Rate-based non-equilibrium models c...