Solvent-based synthesis and characterization of α-Mn(BH4)2 and a new nanoporous polymorph of manganese borohydride, γ-Mn(BH4)2, via a new solvate precursor, Mn(BH4)2·1/2S(CH3)2, is presented. Manganese chloride is reacted with lithium borohydride in a toluene/dimethylsulfide mixture at room temperature, which yields halide and solvent-free manganese borohydride after extraction with dimethylsul...

industries, its nuclear properties in the pure metallic form make it highly desirable for nuclear applications. Zr is highly corrosion resistant and has a high melting point (2128 K) with a low thermal neutron absorption cross-section of Zr T = 0.18 b, which is significantly smaller than that of hafnium Hf T =115 b) (Speer, 1982), an element that coexists with Zr in nature. This makes Zr ideal ...

Zirconium aerosol was ignited and burned in atmospheric pressure air in microgravity using a 2.2-s drop tower. Combustion products were collected and analyzed using electron microscopy. The elemental composition analyses indicated that combustion product compositions fell along two linear traces on a ternary Zr–O–N diagram. Currently, the equilibrium Zr–O–N phases are not characterized at tempe...

As a part of the production of nitride nuclear fuel for use in fast nuclear reactors, zirconium is hydrided followed by nitriding and mixing with uranium nitride. This work concludes a study of unwanted metallic particles present in a powder that is supposed to be a zirconium hydride. Sponge zirconium was hydrided at different temperatures and different time intervals, and the resulting hydride...

In the crystal structure of the title compound, C(4)H(12)N(+)·BH(4) (-), the tetra-methyl-ammonium cations are situated on special positions with site symmetry [Formula: see text]m2. The borohydride anions are situated on special positions with 4mm site symmetry and show rotational disorder around the fourfold axis.

The synthesis of palladium-based trimetallic catalysts via a facile and scalable procedure was shown to yield highly promising materials for borohydride-based fuel cells, which are attractive use in compact environments. This, thereby, provides route more environmentally friendly energy storage generation systems. Carbon-supported were herein prepared by three different routes: using NaBH4-ethy...

The recycling of sodium borohydride poses a huge challenge to the drive towards hydrogen economy. Currently, mechano-chemical, thermo-chemical and electrochemical are only reported methods metaborate into borohydride. Much attention has been devoted mechano-chemical reduction, but little focus methods. This review describes behaviour (BH4−) (BO2−) anions in alkaline solutions. BH4− is stabilize...

TiO2/ZrO2 nanocomposite was obtained by the sonochemical technique. In this method, two separate gels containing zirconium and titanium were prepared and mixed together. The precursor sol of zirconium was prepared from an aqueous solution of ZrCl4. The precursor titanium tetra isopropoxide (TTIP) dissolved in isopropanol. Mixing of Titanium and Zirconium gels was resulted in a yellow TiO2/ZrO2 ...

TiO2/ZrO2 nanocomposite was obtained by the sonochemical technique. In this method, two separate gels containing zirconium and titanium were prepared and mixed together. The precursor sol of zirconium was prepared from an aqueous solution of ZrCl4. The precursor titanium tetra isopropoxide (TTIP) dissolved in isopropanol. Mixing of Titanium and Zirconium gels was resulted in a yellow TiO2/ZrO2 ...