Epoxides have recently been identified as important intermediates in the gas phase oxidation of hydrocarbons, and their hydrolysis products have been observed in ambient aerosols. To evaluate the role of epoxides in the formation of secondary organic aerosols (SOA), the kinetics and mechanism of heterogeneous reactions of two model epoxides, isoprene oxide and α-pinene oxide, with sulfuric acid...

Introduction & Aim: Plant growth regulators (PGR) have same effect as natural plant's hormones and can change the main components in plant samples. Chaerophyllum aureum L. is related to Apiaceae family. Experimental: In this paper the qualitative and quantitative composition of the volatile oils of ‎Chaerophyllum aureum L. were reported after using different...

The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m(3) indoor Teflon chamber. By making in situ measurements of the nitrat...

The effect of NO2 on secondary organic aerosol (SOA) formation from ozonolysis of α-pinene, β-pinene, 1-carene, and limonene was investigated using a dark flowthrough reaction chamber. SOA mass yields were calculated for each monoterpene from ozonolysis with varying NO2 concentrations. Kinetics modeling of the first-generation gasphase chemistry suggests that differences in observed aerosol yie...

Aphids are destructive pests, and alarm pheromones play a key role in their chemical ecology. Here, we conducted detailed analysis of terpenoids the vetch aphid, Megoura viciae, its host plant Pisum sativum using gas chromatography/mass spectrometry. Four major components, (-)-?-pinene (49.74%), (E)-?-farnesene (32.64%), (-)-?-pinene (9.42%) ( +)-limonene (5.24%), along with trace amounts +)-sa...

Abstract. Many monoterpenes have at least two different stereochemical forms, and many biosynthetic pathways are known to favor one product over the other(s). A rapid method was developed used in determination of (-/+)-enantiomeric distributions for ?-pinene, ?-pinene, camphene, limonene, ?-phellandrene as emitted by plant material from six conifer species. The species included pine Pseudotsuga...

Multiple-funnel traps baited with exo-brevicomin and a mixture of cisand transverbenol were used to test the relative attractiveness #If myrcene and (-)-a-pinene to the mountain pine beetle, Dendroctonus ponderosae Hopkins, in a s tand of western white pine, Pinus mont icola Doug]. Traps baited with myrcene caught significantly more D. ponderosae than traps baited with (-)-a-pinene, irrespectiv...

The essential oils associated with the flowers of Tithonia diversifolia (Hemsl.) A. Gray were extracted and characterized via hydrodistillation and Gas Chromatography. Hydrodistillation was done in an all-glass Clevenger-type apparatus. The extracts from the hydrodistillation were subjected to gas chromatography where the components of the essential oils were separated based on their molecular ...

We have a continuing interest in applying the current knowledge of cytochrome P450cam substrate recognition to engineer the enzyme for the biotransformation of unnatural substrates with the long-term aim of applications in the synthesis of fine chemicals and bioremediation of environmental contaminants. Comparisons of the structure of target substrates with that of camphor, the natural substrat...

Oleoresin samples collected from Pinus sylvestris L. trees from Acıpayam, Çal and Çamlıbel, three different locations in Denizli-Turkey. The constituents of the turpentine oil, obtained by hydrodistillation of oleoresin of Pinus sylvestris L., were identified by GC-MS. Fifty four constituents were detected from the turpentine oil, which constituted about between 96.2% and 98.2% of the total amo...