Excess phosphorus (P) in wastewaters promotes eutrophication in receiving waterways. A cost-effective method such as use of novel low-cost adsorbents for its adsorptive removal would significantly reduce such impacts. Using batch experiments, the intrinsic dynamics of P adsorption by waste alum sludge (an inevitable by-product of drinking water treatment plants) was examined. Different models o...

Adsorption of lead(II) as a major heavy metal pollutant onto nano-adsorbents of Andalusite, Kyanite and Sillimanite was studied in a batch system. Nano­-adsorbents were prepared via crushing, using a planetary ball mill and then characterized by different analyses such as: SEM, XRD, XRF and FT-IR. Major factors affecting the adsorption process were studied including pH, adsorbents dosage, initi...

in this research new adsorbents were prepared by modification of surfactant-coated g-alumina with three ligands; 1-(2-pyridylazo)-2-naphtol (pan), dithizone (hdz) and dimetyl golyoxime (dmg). the adsorbents were used for removal and pre-concentration of pb+2, cd+2, ni+2, cu+2, co+2. aqueous solutions of the metal ions were passed through a column filled with the adsorbent and the retained catio...

Water scarcity and its contamination with toxic metal ions and organic dyes represent a serious worldwide problem in the 21st century. A wide range of conventional approaches have been used to remove these contaminants from waste. Recently, nanotechnology has been given great scope for the fabrication of desirable nanomaterials with large surface-to-volume ratios and unique surface functionalit...

We have analyzed the lectin binding characteristics of cytotoxic T lymphocyte (CTL)-derived surface labeled glycoproteins by affinity chromatography of the labeled glycoproteins on a panel of immobilized lectin adsorbents. Evidence is presented for the specific interaction of the CTL-associated glycoprotein T 145 with a lectin derived from Vicia villosa seeds. Conditions are described for the p...

In this quantum chemical investigation, NH(3) physisorption onto a model of copper sulfate impregnated silica is compared with pure silica and copper sulfate adsorbents. The physisorption process is modeled as direct binding of the NH(3) molecule to the adsorption site of the dry adsorbents and as displacement of a H(2)O molecule by NH(3) in the hydrated complexes. The surface of silica is repr...

Ergot alkaloids, in their active isomeric form, affect animal health and performance, and adsorbents are used to mitigate toxicities by reducing bioavailability. Adsorbents with high specificity (molecularly imprinted polymers: MIP) adsorb ergot alkaloids in vitro, but require evaluation for biological implications. Using ex vivo myography, synthetic polymers were evaluated for effects on the b...

Silica monolith aerogels with different degrees of hydrophobicity by incorporating methyltrimethoxysilane (MTMS) or trimethylethoxysilane (TMES) in standard sol-gel synthesis were prepared. Excellent properties of aerogels, obtained with the sol-gel synthesis, were preserved with supercritical drying with CO2. The degree of hydrophobicity of the aerogels was tested by measuring the contact angl...

Perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) have increasingly attracted global concerns in recent years due to their global distribution, persistence, strong bioaccumulation and potential toxicity. The feasibility of using powder activated carbon (PAC), granular activated carbon (GAC) and anion-exchange resin (AI400) to remove PFOS and PFOA from water was investigated with re...

The membrane bioreactor (MBR) has emerged as an efficient compact technology for municipal and industrial wastewater treatment. The major drawback impeding wider application of MBRs is membrane fouling, which significantly reduces membrane performance and lifespan, resulting in a significant increase in maintenance and operating costs. Finding sustainable membrane fouling mitigation strategies ...