The complexation of uranyl ions with lipopolysaccharide (LPS), the main component of the cell wall of Gram-negative bacteria, was investigated on a molecular level with U L(III)-edge extended X-ray absorption fine structure (EXAFS) and attenuated total reflection Fourier transform infrared (ATR-FT-IR) spectroscopy over a wide pH range (2.6 to 7.0). For the first time, structural determinations ...

In this study, we examined the effects of simultaneous adsorption of aqueous arsenate and uranyl onto aluminum oxide over a range of pH and concentration conditions. Arsenate was used as a chemical analog for phosphate, and offers advantages for characterization via X-ray absorption spectroscopy. By combining batch experiments, speciation calculations, X-ray absorption spectroscopy, and X-ray d...

An annular denuder system, which consisted of a cyclone separator; two diffusion denuders coated with sodium carbonate and citric acid, respectively; and a filter pack consisting of Teflon and nylon filters in series, was used to measure acid gases, ammonia (NH3), and fine particles in the atmosphere from April 1998 to March 1999 in eastern North Carolina (i.e., an NH3-rich environment). The so...

The complex chemistry of uranyl nitrate with mono and bi-functional neutral extractants shows, that it forms 1:2 and 1:1 complexes respectively. The structures of the isolated complexes show, that the water molecules from the primary coordination sphere of [UO2(NO3)2.2H2O] are replaced by the extractants completely and adopt a hexagonal bi-pyramidal geometry. However, the structural chemistry o...

The aim of the study is to determine chemical and physical properties gallstones Antalya province. In line with this, mineralogical characteristics 1243 gallstone samples from 69 patients were analyzed, using scanning electron microscopy (SEM) Fourier-transform infrared spectroscopy (FTIR) analysis. 
 Cholesterol, carbonate apatite, calcium carbonate, phosphate bilirubinate, protein conten...

An optimum carrier rugosity is essential to achieve a satisfying drug deposition efficiency for the carrier based dry powder inhalation (DPI). Therefore, a non-organic spray drying technique was firstly used to prepare nanoporous mannitol with small asperities to enhance the DPI aerosolization performance. Ammonium carbonate was used as a pore-forming agent since it decomposed with volatile dur...

Synthesis of protein amides from ammonia has been proposed (Bliss (1)) as a tissue function whose demonstration is of cardinal importance to the development of the theory that blood protein amide nitrogen represents detoxified ammonia, first employed in tissues for neutralization of acid, in course of transport to the kidneys where the amide nitrogen reappears as urinary ammonia. Questionable i...

Ferrite grade zinc oxide was prepared through aqueous processing of zinc ash followed by calcination. Zinc was quantitatively dissolved in sulphuric acid medium. The ferrous iron present in the leach solution was oxidised with hydrogen peroxide followed by precipitation of total iron by pH adjustment to 4.5 with dilute sodium hydroxide solution. Copper was removed by cementation using zinc dust...

BACKGROUND A reliable quenching and metabolite extraction method has been developed for Lactobacillus plantarum. The energy charge value was used as a critical indicator for fixation of metabolism. RESULTS Four different aqueous quenching solutions, all containing 60% of methanol, were compared for their efficiency. Only the solutions containing either 70 mM HEPES or 0.85% (w/v) ammonium carb...