A series of aromatic hydrocarbons were investigated so as to compare the reactivity of corannulene with planar aromatic hydrocarbons. Corannulene was found to be more reactive than benzene, naphthalene and triphenylene to Friedel-Crafts acylation whilst electrophilic aromatic bromination was also used to confirm that triphenylene was less reactive than corannulene and that pyrene, perylene and ...

kharg island as the most important oil export terminal of iran has faced entrance of various oilmaterials, so it seems necessary to know about the amount of these marine oil pollutants and their origin in this area. oil hydrocarbons has entered in this water body as a result of numerous human activities like extraction, refinement, transmission and export of raw oil or from natural and biologic...

This paper examines the possible presence, distribution, nature and sources of 18 Polycyclic Aromatic Hydrocarbons (PAHs) as constituent of the muds pool collected in Vulcano Aeolian Island. PAHs are important from environmental and toxicological point of view. Analysis was performed by gas chromatography/mass spectrometry (GC/MS) in selected ion monitoring (SIM). The total concentration of Pol...

Polycyclic aromatic hydrocarbons (PAHs) in water ice were exposed to ultraviolet (UV) radiation under astrophysical conditions, and the products were analyzed by infrared spectroscopy and mass spectrometry. Peripheral carbon atoms were oxidized, producing aromatic alcohols, ketones, and ethers, and reduced, producing partially hydrogenated aromatic hydrocarbons, molecules that account for the i...

The ionization potentials (IP) of 91 alternant polycyclic aromatic hydrocarbons (PAH) were determined from the absorption maximum of the charge-transfer complex of each hydrocarbon and chloranil in chloroform. The extent of horseradish peroxidase (HRP)-catalyzed binding to DNA of 14 hydrocarbons of varying IP was measured. Only hydrocarbons with IP less than approx. 7.35 eV were significantly b...

Volatile organic chemicals present at Superfund sites preferentially partition into the soil gas and may be available for microbial degradation. A simple mass transfer model for biodegradation for volatile substrates has been developed for the aerobic decomposition of aromatic and aliphatic hydrocarbons. The mass transfer analysis calculates diffusive fluxes from soil gas through water and memb...

An interesting feature of elemental boron and boron compounds is the occurrence of highly symmetric icosahedral clusters. The rich chemistry of boron is also dominated by three-dimensional cage structures. Despite its proximity to carbon in the periodic table, elemental boron clusters have been scarcely studied experimentally and their structures and chemical bonding have not been fully elucida...

polycyclic aromatic hydrocarbons (pahs) which are toxic pollutants are released by various sources of urban combustion. ahvaz in iran with around a million population and the industrial and oil centers, has encountered air quality problems. samples of dibenzo (a,h) antheracen were collected from six stations in ahvaz particle and gas phase in summer 2010. dibenzo(a,h) antheracen were collected ...

A pathway of research is described, leading from the finding of an inhibitory effect of 3-methylcholanthrene on the carcinogenicity of an aminoazo dye, to the induction of drug-metabolizing enzymes by 3-methylcholanthrene, benzo[a]pyrene, and other polycyclic aromatic hydrocarbons, to the demonstration of enhanced drug metabolism in cigarette smokers, coffee drinkers, and people who eat charcoa...