The thermodynamics of fluoride ion solvation in nonaqueous and mixed aqueous solvents are reviewed. Gibbs energies of transfer , at^ O (F ) H20+ , indicate that the solvation of the fluoride ion is dominated by hydrogen bonding. Thus, at^ o ( ~ ) H 2 0 S is unfavourable for virtually all solvents, especially dipolar aprotics, and correlates well with solvent acceptor strength. The corresponding...

In this research, the new separation method based on micro solvent cluster extraction and preferential solvation has been described. A proposed separation method using aqueous mixed solvents of organic solvents (acetonitrile, 1-propanol, 2-propanol and 1,1,1,3,3,3-hexafluoro-2-propanol) or ionic liquids and an open tubular capillary has been separated the model compounds (2-naphthol, 4-nitroani...

We explore solvent dynamics effects in interfacial bond breaking electron transfer in terms of a multimode approach and make an attempt to interpret challenging recent experimental results (the nonmonotonous behavior of the rate constant of electroreduction of S2O8(2-) from mixed water-EG solutions when increasing the EG fraction; see Zagrebin, P.A. et al. J. Phys. Chem. B 2010, 114, 311). The ...