This work, for the first time, experimentally demonstrates the relationship between motor vehicle emissions and the decay of ornamental calcareous stone, by means of sulfation processes (the well-known phenomenon of Black-crust formation). The critical catalytic effects of carbon (soot) and metal-rich particles from vehicle exhaust result in the acceleration of the rate of fixation of atmospher...

The development of a cascaded feedback control strategy for a vapor-phase axial deposition (VAD) process is investigated in this paper. VAD is a widely used process in the creation of high purity glass for optical fiber. In previous work a soot tip surface temperature controller was developed for the VAD process to reduce the effects of core soot temperature variation on deposition, leading to ...

In this work we present a numerical iterative procedure for the evaluation of the effect of signal absorption in two-color laser-induced incandescence (2C-LII) measurements. The correction process is applied to experimental results, previously published by our group, in an axisymmetric diffusion flame. We have studied the influence of signal trapping on peak soot temperature and on soot volume ...

The purpose of this paper is to address the differences observed in the oxidative kinetics between flame and diesel derived soots. In particular, it has been observed that flame soot has a significantly higher activation energy for oxidation than does diesel soot. The hypothesis tested in this paper is that metals, possibly coming from lubricating oils, within diesel generated soot particles ma...

Several series of chronic experiments in white mice and white rats were carried out in order to determine the carcinogenicity of Estonian oil shale soot as well as the soot from oil shale fuel oil. All the investigated samples of soot showed a relatively low (from 14 to 1200 ppm) benzo(a)pyrene content. The benzene extract of oil shale soot, painted on the skin of white mice, proved to be stron...

A CFD-based numerical model has been developed for the determination of the volume concentration and number density of soot in a laminar diffusion flame of methane in air, under transient condition following ignition of the flame. The transience is studied from the point of ignition till the final steady state is reached. The burner is an axi-symmetric co-flowing one with the fuel issuing throu...

Detailed modeling of an experimental ethylene/air jet flame is undertaken using the composition PDF method for gas-phase kinetics coupled with detailed models for soot formation and radiation from the flames. The gas-phase kinetics is modeled using a reduced mechanism for ethylene consisting of 33 species and 205 elementary reactions. The soot formation is modeled using the method of moments wi...

The formation of soot particles in combustion depends on several factors that include: pressure, temperature, fuel chemical structure and extent of premixing. An improved version of the thermophoretic particle densitometry (TPD) method, has been used in this study for quantitative and qualitative characterization of soot particles generated in laminar partially-premixed co-flow flames having di...

In this study an expression for soot absorption coefficient is introduced to extend the weighted-sum-of-gray gases data to the furnace medium containing gas-soot mixture in a utility boiler 150 MWe. Heat transfer and temperature distribution of walls and within the furnace space are predicted by zone method technique. Analyses have been done considering both cases of presence and absence of soo...

Although diesel engines have an advantage of low fuel consumption compared with gasoline engines, several problems must be solved. One of the major concerns is that diesel exhaust gas has more particulate matters (PM) including soot, which are suspected to be linked to human carcinogen. As one of the key technologies, a diesel particulate filter (DPF) has been developed to reduce PM in the afte...