The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Abstract Efficient and scalable solution-based processes are not generally available to integrate well-studied pseudocapacitive materials (i.e., metal oxides and conducting polymers) with other components such as porous carbon, mainly because these classes of pseudocapacitive s...

The synthesis of hollow carbon nanospheres or capsules has attracted considerable attention because of their potential applications in catalyst supports, fuel cells, gas storage and separation, and lithium-ion batteries, which result from their unique features, such as high surface-to-volume ratio and high structural stability. Templating is the method widely used to synthesize hollow carbon sp...

In this study, we demonstrate a rapid treatment method for producing a needle-like nanowire structure on a hot-dip galvanized sheet at a temperature of 50 °C. The processing method involved only supercritical carbon dioxide and water to induce a reaction on the zinc surface, which resulted in growth of zinc hydroxycarbonate nanowires into flower-like shapes. This artificial patina nanostructure...

This research investigates changes in the nanostructure and the nanoscale local mechanical properties of cement paste with microand nano-modifiers. Silica fume and multiwall carbon nanotubes (MWCNTs) were used as microand nano-modifiers. An effective method of dispersing CNTs in cement matrix was developed. A detailed study on the effects of CNTs concentration and aspect ratio on the fracture p...

We report the preparation of thermally tunable hydrogels displaying angle-independent structural colors. The porous structures were formed with short-range order using colloidal amorphous array templates and a small amount of carbon black (CB). The resultant porous hydrogels prepared using colloidal amorphous arrays without CB appeared white, whereas the hydrogels with CB revealed bright struct...

The functionalization of carbon based nanomaterials could have applications in atmospheric chemistry and contaminants removal. In this work, a quantum chemistry and computational kinetics study has been performed on the OH radical addition to ethylene previously adsorbed on a model surface of graphene. Rate constants are calculated and compared with the ethylene + OH gas phase reaction, for whi...

We describe in situ synthesis and characterization of single-walled BN nanotubes terminated by fullerenelike structures using electron-cyclotron resonance nitrogen and electron beam boron sources onto polycrystalline tungsten substrates. Detailed comparisons of experimental high-resolution electron microscopy images and simulations based upon molecular models show a dominance of kinks and bends...

Next-generation electronic, photonic or spintronic devices will be based on nanoscale functional units, such as quantum dots, isolated spin centres or single-molecule magnets. The key challenge is the coupling of the nanoscale units to the macroscopic world, which is essential for read and write purposes. Carbon nanotubes with one macroscopic and two nanoscopic dimensions provide an excellent m...