Crystal engineering has recently emerged as a method of choice for the design and construction of organic as well as metal-organic functional materials. Crystal engineering attempts to establish packing trends in whole families of compounds and seeks to establish connections between structure and function. The utility of crystal engineering has also been expanded to the nanoscience and the deve...

Cellulose is a biopolymer that has long been used as a biomaterial and its different sources, as Bacterial Cellulose (BC), have shown to possess impressive mechanical properties, which can lead to the development of new biomedical implants. Bacterial Cellulose is a polysaccharide secreted by bacteria as Gluconacetobacter xylinus: BC is composed of highly hydrated nanofibrils and it is character...

We demonstrate for the first time that cellulose nanofibers obtained from natural sources have the capability to hydrolyze the amide bonds of amino acid substrates in a chirality-specific manner. The chiral specificities were clearly correlated with the species of amino acid units and the crystal structures of cellulose.

Biodirected epitaxial nanodeposition of polymers was achieved on a template with an oriented molecular surface. Acetobacter xylinum synthesized a ribbon of cellulose I microfibrils onto a fixed, nematic ordered substrate of glucan chains with unique surface characteristics. The substrate directed the orientation of the motion due to the inverse force of the secretion during biosynthesis, and th...

The objective of this work was to develop an environmental friendly method for the effective utilization of coir fibre by adopting steam pre-treatment. The retting of the coconut bunch makes strong environmental problems which can be avoided by this method. Chemical characterization of the fibre during each processing stages confirmed the increase of cellulose content from raw (40%) to final st...

The salient feature of liquid crystal elastomers and networks is strong coupling between orientational order and mechanical strain. Orientational order can be changed by a wide variety of stimuli, including the presence of moisture. Changes in the orientation of constituents give rise to stresses and strains, which result in changes in sample shape. We have utilized this effect to build soft ce...

The molecular deformation and crystal orientation of a range of next generation regenerated cellulose fibers, produced from an ionic liquid solvent spinning system, are correlated with macroscopic fiber properties. Fibers are drawn at the spinning stage to increase both molecular and crystal orientation in order to achieve a high tensile strength and Young’s modulus for potential use in enginee...

Currently, Malaysia has significantly increased its reputation as a country ripe for investments in the palm-based lignocellulosic biomass space. Lignocellulosic palm biomass is composed of cellulose, hemicellulose and lignin, as well as other minor components. The presence of highly cellulose content in palm biomass is potentially convert to nanocellulose, which is a promising bio-polymer that...

A combination of reinforcements at different levels can have a synergetic effect on the final properties of a composite. The aim of this work was to produce, evaluate, and compare the wet/dry cycling durability of the exposure of cement composites reinforced with conventional pulps at the micro-scale level, with nanofibrillated cellulose fibers at the nano-scale level, and with combinations of ...

zno nanorod was prepared by microwave assisted method. the crystal structure of the nano powders were confirmed by x-ray diffraction analysis and the mean particle size was estimated by the scherrer,s formula .the surface morphology of the nano particles were analyzed by   using sem . the absorption spectrum of the material in the uv-vis range was recorded .the energy band gap of the material w...