نتایج جستجو برای: charge transfer reaction
تعداد نتایج: 805518 فیلتر نتایج به سال:
We present a theoretical approach to investigate the electron spin polarization (ESP) of the excited triplet state that has been detected by using the time-resolved EPR (TREPR) method in the Photosystem II reaction center (PS II RC) of the plants. We show, by using the stochastic-Liouville equation, that the ESP pattern created in the accessory chlorophyll (ChlaccD1) which reside near the PD1 c...
The heteroaromatic polynitrile compound tetracyanopyridine (TCNPy) is introduced as a new electron acceptor for the formation of deeply colored charge-transfer complexes. In MeCN, TCNPy is characterized by a quasireversible one-electron-reduction process at -0.51 V (versus SCE). The tetracyanopyridine radical anion undergoes a secondary chemical reaction, which is assigned to a protonation step...
The purple bacterial reaction centre uses light energy to separate charge across the cytoplasmic membrane, reducing ubiquinone and oxidizing a c-type cytochrome. The protein possesses a macroscopic structural two-fold symmetry but displays a strong functional asymmetry, with only one of two available membrane-spanning branches of cofactors (the so-called A-branch) being used to catalyse photoch...
the formation of charge-transfer complexation between dibenzo-15-crown-5 (db15c5) and benzo-12-crown-4 (b12c4) (donor) and iodine is investigated spectrophotometrically in three chlorinated solvents,chloroform, dichloromethane (dcm) and 1,2-dichloroethane (dce) solution at 25°c. the change in polarityof the solvent also doesn’t affect the stoichiometry of the complexes. values of formation cons...
Charge transfer through biological macromolecules is essential for many biological processes such as, for instance, photosynthesis and respiration. Protons or electrons are transferred between titratable residues or redox-active cofactors, respectively. Transfer rates between these sites depend on the current charge configuration of neighboring sites. Here, we formulate the kinetics of charge-t...
Long-distance transfer of a positive charge through DNA can be described by a hopping model. In double strands where the (A:T)n bridges between the guanines are short (n ≥ 3), the charge hops only between guanines, and each hopping step depends strongly upon the guanine to guanine distances. In strands where the (A:T)n sequences between the guanines are rather long (n ≥ 4), also the adenines ac...
Proton recoil polarization was measured in the quasielastic 4He(e,e'p)3H reaction at Q{2}=0.8 and 1.3 (GeV/c){2} with unprecedented precision. The polarization-transfer coefficients are found to differ from those of the 1H(e,e'p) reaction, contradicting a relativistic distorted-wave approximation and favoring either the inclusion of medium-modified proton form factors predicted by the quark-me...
The response mechanism of the iron(III) chalcogenide glass membrane ion-selective electrode (ISE) in saline media has been studied using electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). EIS equivalent circuits and XPS surface compositions for the FeIII ISE are consistent with the presence of two surface films probably comprising a outer surface layer (OSL...
The dynamics of electron transfer reactions in solution can be controlled with the use of a sequence of femtosecond laser pulses. In the charge transfer to solvent (CTTS) reaction of sodide (Na-) in tetrahydrofuran, an initial light pulse launched the CTTS reaction, ejecting an electron into either an immediate or a solvent-separated Na0:solvated electron contact pair. A second pulse was used t...
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