The construction and performance characteristics of a novel chromate ion-selective membrane sensor are described and used for determining chromium(III) and chromium(VI) ions. The sensor is based on the use of a rhodamine-B chromate ion-associate complex as an electroactive material in a poly(vinyl chloride) membrane plasticized with o-nitrophenyloctyl ether as a solvent mediator. In a phosphate...

background: the presence of heavy metals in the environment especially in water supplies have caused many concerns because of their toxicity and non-degradability. hexavalent chromium (cr) is one of the most toxic metals which is used in many industries, so it is essential to remove it from industrial wastewater. in this study, we made a comparison between different adsorption isotherms in the ...

* Corresponding author The potential to remove Cr (VI) from aqueous solutions through biosorption using the husk of Bengal gram (Cicer arientinum), was investigated in batch experiments. The results showed removal of 99.9% of chromium in the 10 mgl chromium solution, the biomass required at saturation was 1 g mg. Kinetic experiments revealed that the dilute chromium solutions reached equilibriu...

in parts of desert regions in our country, groundwater is the only source of fresh water and due to geological formation, the concentration of hexavalent chromium in groundwater will reach beyond the allowed limits. furthermore, previous studies showed that hexavalent chromium is a cancerous substance for humans and toxic for other organisms. in this study the removal of hexavalent chromium fro...

The adsorption of chromium(VI) ions from aqueous solutions has been investigated on Neem sawdust (NS), Mango sawdust (MS), Wheat shell (WS), Sugarcane bagasse (SB) and Orange peel (OP). The adsorbent which showed highest chromium(VI) removal was Neem sawdust. The influence of pH, contact time, biomass dosage and initial metal concentration on biosorption was investigated. The biosorptive capaci...

Chromium is one of the 25 most widespread elements in the Earth’s crust and occurs as an indelible non-volatile trace element in raw materials used in cement clinker production (clay, limestone and iron additives in particular). Chromium in raw materials mentioned above is mainly in form of trivalent chromium. Naturally occurring chromium (III) is not initially harmful, since it is chemically s...

BACKGROUND Chromium (VI) has toxic and carcinogenic effects. So, determination and speciation of chromium in environmental samples is very important in view of health hazards. In this study, solid phase extraction (SPE) based on bulky amine-functionalized bimodal mesoporous silica nanoparticles (NH2-UVM-7) as a novel nanoadsorbent was applied for preconcentration and speciation of chromium (III...

Chromium exists in many different oxidation states in the environment, Cr(VI) and Cr(III) being the most stable forms. Chromium has been known for over 100 years to be a human carcinogen. The greatest risk of cancer from chromium exposure is associated with Cr(VI). Cr(VI) enters cells via the sulfate anion transporter system and is reduced to intermediate oxidation states, such as Cr(V) and Cr(...