the effect of alkyl substituents on the c-phenyl and/or the n-phenyl ring of benzophenylhydroxamic acid on their molecular structure and hydrogen bonding has been investigated. the predominant configuration in chcl3 is determined by steric and electronic effects. substituents on the c-phenyl ring favor the cis configuration, while substituents in the n-phenyl ring favor a trans configuration. t...

ferulago angulata (apiaceae), a medicinal plant of western asia, contains essential oils that areused as a food preservative. this study examined and compared the composition of leaf oil with seed oil andof the oils from two different habitats (one from nevakov and the other from shahoo). the oil yield from seedwas 5-fold that from leaves (3.2%/100g compared to 0.63%/100g). cis-ocimene was the ...

in the present study, theoretical chemical reactivates photo isomerization in cis-retinal as a natural photo switch in vision. dft hybrid functional, b3lyp and, post-hf method, were the theoretical methods applied utilizing g09 software. 6-31g+ (d,p) basis set employed for structural optimizations, and single point computations performed using b3lyp/6-31g+(d,p). the isomers cis molecule retinal...

En este artículo se reportan resultados experimentales de interacciones del aminoácido L-cisteína (Cis) con nanopartículas oro (AuNPs) y funcionalizadas Cis (AuNPs+Cis) cuando incorpora en la solución iones As3+. los procesos agregación evalúa el papel concentración funcionalización, además tamaño las a agente iónico interés. Los muestran una sensible dependencia nanosondas AuNPs+Cis función su...