Abstract The study investigates hydrogenation of CO 2 over mono- and bimetallic catalysts supported on biochar. In this reaction, iron–cobalt were shown to surpass monometallic iron cobalt in terms catalytic performance. optimal combination performance parameters was reached at an ratio 3 : 1. composition genesis the active phase Fe–Co catalyst identified, mechanism suggested for iron-dominated...

Ammonia generation through reaction of H(2) with neutral cobalt nitride clusters in a fast flow reactor is investigated both experimentally and theoretically. Single photon ionization at 193 nm is used to detect neutral cluster distributions through time-of-flight mass spectrometry. Co(m)N(n) clusters are generated through laser ablation of Co foil into N(2)/He expansion gas. Mass peaks Co(m)NH...

The commercial application of cobalt-based Fischer-Tropsch synthesis (FTS) suffers from catalyst deactivation. One the main deactivation mechanisms under industrial conditions is sintering. In this work, we explored role manganese oxide as a structural promoter against sintering in carbon nanofiber supported cobalt model catalyst. We employed situ Mössbauer emission spectroscopy to study gas fu...

A cobalt catalyst (25%Co/γ-Al2O3, prepared by slurry phase impregnation) was used in a fixed bed reactor under a pressure/density tuned supercritical fluid mixture of n-pentane/nhexane. By using an inert gas as a balancing gas to maintain a constant pressure, the density of the supercritical fluid could be tuned near the supercritical point while maintaining constant space velocity within the r...

Introduction Industrial higher olefin (> C5) hydroformylation processes require harsh temperatures and pressures (140 200 oC, 5 30 MPa) as well as tedious catalyst separation schemes involving hazardous reagents to recycle the cobalt catalyst [1]. The use of rhodium (Rh) as a catalyst would lower the operating temperature and pressure but requires almost quantitative recovery and recycle of the...

An extensive study of Fischer-Tropsch synthesis (FTS) on alumina-supported cobalt catalysts promoted with different amounts of ruthenium and rhenium is reported. Up to 2 wt% of promoters, are added to the catalyst by coimpregnation. The catalysts are characterized by different methods including: BET physisorption, X-ray diffraction, hydrogen chemisorption, and temperature-programmed reducti...

Three cobalt complexes bearing tunable, redox-active bipyridyl N-heterocyclic carbene (NHC)-based ligands have been studied for electrocatalytic hydrogen evolution from aqueous solutions. The effect of structural modifications to the ligand framework is investigated across catalyst series, which includes a non-macrocyclic derivative (1-Co) and 16-(2-Co) 15-(3-Co) membered macrocycles. A structu...

Key words photpcatalysis - metal-organic layer cobalt catalyst dehydrogenative amination

Strong and versatile carbon nanotubes (CNTs) are finding new applications in improving conventional polymer-based fibers. Nanotube-reinforced composites could ultimately provide the foundation for a new class of strong and lightweight fibers with properties such as electrical and thermal conductivity unavailable in current fibers. A recent research has discovered that the best type of nanotube ...