Pd(0) is able to catalyze oxygen-involving reactions because of its capability to convert molecular oxygen to the very reactive atomic form. Consequently, the embedding of a little amount of Pd(0) clusters in polymeric phases can be technologically exploited to enhance the incineration kinetic of these polymers. The effect of nanostructuration on the Pd(0) catalytic activity in the polymer inci...

Nanomaterials with characteristic structural dimensions on the order of few nanometers (1–100 nm) attract wide attention owing to their unique properties. They found a variety of applications in different branches of science and industry including catalysis, micro and biotechnologies, energy storage and conversion devices, such as fuel cells. Different techniques have been developed for nanomat...

Ignition and reaction kinetics of silane/oxygen/diluent (SiH4/O2/Ar/N2) mixtures have been studied using a rapid compression facility (RCF). Time-resolved pressure profiles and absolute, quantitative hydroxyl radical mole fraction (χOH) time histories were obtained for a range of conditions representing different heating rates. At the moderate temperatures studied (∼630 K), ignition was observe...

The blue-emitting phosphor cerium activated yttrium silicate, (Y1 mCem)2SiO5, was prepared via a novel synthesis technique called combustion synthesis. Combustion synthesis involves a highly exothermic redox reaction between metal nitrates and an organic fuel to produce a solid powder. The combustion synthesis parameter, the fuel-to-oxidizer ratio, has a direct effect on the physical properties...

Computational fluid dynamic (CFD) modeling of full-scale catalytic converters with realistic chemistry has remained elusive primarily due to the extreme computational requirements. In this work, a new low-memory coupled implicit solver, based on the conservative unstructured finite-volume method, was utilized to simulate laboratory-scale catalytic converters with implicit coupling between fluid...

A detailed chemistry-based CFD model was developed to simulate the diesel spray combustion and emission process. A reaction mechanism of n-heptane is coupled with a reduced NOx mechanism to simulate diesel fuel oxidation and NOx formation. The soot emission process is simulated by a phenomenological soot model that uses a competing formation and oxidation rate formulation. The model is applied ...

Mineral calcination worldwide accounts for some 5–10% of all anthropogenic carbon dioxide (CO2) emissions per year. Roughly half of the CO2 released results from burning fossil fuels for heat generation, while the other half is a product of the calcination reaction itself. Traditionally, the fuel combustion process and the calcination reaction take place together to enhance heat transfer. Syste...

The theory of reaction-diffusion waves begins in the 1930s with the works in population dynamics, combustion theory and chemical kinetics. At the present time, it is a well developed area of research which includes qualitative properties of travelling waves for the scalar reaction-diffusion equation and for system of equations, complex nonlinear dynamics, numerous applications in physics, chemi...

In recent years, a large number of linear and nonlinear laser-based diagnostic techniques for non-intrusive measurements of species concentrations, temperatures, and gas velocities in a wide pressure and temperature range with high temporal and spatial resolution were developed and have become extremely valuable tools to study many aspects of combustion. Nonlinear laser spectroscopic techniques...