A new method to generate chemical reaction network is proposed. The particularity of the method is that network generation and mechanism reduction are performed simultaneously using sampling techniques. Our method is tested for hydrocarbon thermal cracking. Results and theoretical arguments demonstrate that our method scales in polynomial time while other deterministic network generators scale ...

a comparison between design codes i.e. aci and aisc-lrfd in evaluation of flexural strength of concrete filled steel tubular columns (cfts) is examined. for this purpose an analytical study on the response of cfts under axial-flexural loading is carried using three-dimensional finite elements with elasto-plastic model for concrete with cracking and crushing capability and elastoplastic kinemati...

We investigated the process of nut-cracking acquisition in a semi-free population of tufted capuchin monkeys (Sapajus sp) in São Paulo, Brazil. We analyzed the cracking episodes from monkeys of different ages and found that variability of actions related to cracking declined. Inept movements were more frequent in juveniles, which also showed an improvement on efficient striking. The most effect...

For many years, researchers have been developing theoretical methods of estimating reaction rates and energetics when experimental measurements are not available. Recent advances have led to composite energy methods with near chemical accuracy. The performance of these new methods for predicting activation energies and rate constants have not been evaluated for large hydrocarbon cracking reacti...

INTRODUCTION Secondary hyperparathyroidism in end-stage renal disease patients has protean musculoskeletal manifestations. Some of our dialysis patients spontaneously vocalized that they had lost the ability to crack their knuckles and then experienced gratifying restoration after surgical parathyroidectomy. We propose that the physiology and mechanical basis of knuckle cracking would be affect...

Understanding the mechanism of cracking during the drying of aqueous colloidal dispersions is important to preventing film failure. While most of the reported work has dealt with stable aqueous dispersions, a few studies have focused on flocculated systems. The latter especially assumes importance because the role of particle packing in the mechanism of cracking is not completely understood. In...

Concrete and cracking are nearly synonymous despite our best efforts and intentions. Relationships between cracking and the stress states that lead to cracking can be instructive. In an effort to better understand these relationships, X-ray microtomography was used to make high-resolution three-dimensional digital images of small concrete specimens under load. Using 3D image analysis, quantitat...

Culture extends biology in that the setting of development shapes the traditions that individuals learn, and over time, traditions evolve as occasional variations are learned by others. In humans, interactions with others impact the development of cognitive processes, such as sustained attention, that shape how individuals learn as well as what they learn. Thus, learning itself is impacted by c...

The kinetics of alkane cracking in zeolites MFI and FAU have been simulated theoretically from first principles. The apparent rate coefficient for alkane cracking was described as the product of the number of alkane molecules per unit mass of zeolite that are close enough to a Brønsted-acid site to be in the reactant state for the cleavage of a specific C-C bond and the intrinsic rate coefficie...