نتایج جستجو برای: critical micelle concentration

تعداد نتایج: 848551  

2001
Frank H. Quina Patricia M. Nassar Barney L. Bales

Sodium alkyl sulfate micelles are predicted to grow as a power law of the total counterion salt concentration, Yaq, in the aqueous phase as follows: NA = K~(Y~~)Y, where N A is the micelle aggregation number and ~2 and y are constants which are estimated from the critical micelle concentration and the apparent degree of counterion attachment. For sodium dodecyl sulfate, NA = 162(Y,q)1/4 is pred...

Journal: :Molecules 2014
Caili Dai Mingyong Du Yifei Liu Shilu Wang Jianhui Zhao Ang Chen Dongxu Peng Mingwei Zhao

Micelles formed by the long-chain piperidinium ionic liquids (ILs) N-alkyl-N-methylpiperidinium bromide of general formula CnPDB (n = 12, 14, 16) in ethylammonium nitrate (EAN) were investigated through surface tension and dissipative particle dynamics (DPD) simulations. Through surface tension measurements, the critical micelle concentration (cmc), the effectiveness of surface tension reductio...

2013
Taliha Sidim Gökhan Acar

In this research, the micellar behavior of a cationic surfactant, cetyl trimethyl ammonium bromide (CTAB) and an nonionic surfactant, polysorbate 20 (Polyoxyethylene (20) sorbitan monolaurate) in different alcohol solutions media was investigated over the temperature range 293.15-313.15 K. The interaction between two surfactants in binary systems can be determined by calculating the values of t...

2014
P. A. Kralchevsky K. D. Danov

Here, we review two recent theoretical models in the field of ionic surfactant micelles and discuss the comparison of their predictions with experimental data. The first approach is based on the analysis of the stepwise thinning (stratification) of liquid films formed from micellar solutions. From the experimental step wise dependence of the film thickness on time, it is possible to determine t...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 1976
P Boquet M S Silverman A M Pappenheimer W B Vernon

Binding of the nonionic detergent [3H]Triton X-100 by diphtheria toxin, by the nontoxic serologically related protein crossreacting material (CRM) 45, and by their respective A and B fragments has been studied. If first denatured in 0.1% sodium dodecyl sulfate, all of the proteins with the exception of fragment A bind increasing amounts of Triton X-100, reaching a maximum of more than 40 mol bo...

Naser Akhlaghi Siavash Riahi

The interfacial tension of surfactant solutions is decreased with increasing surfactant concentration to obtain the critical micelle concentration (CMC). After that, the CMC values does not alter much. So this concentration is a critical point during surfactant flooding that is one of the chemical EOR techniques. The reduction of the CMC value is taken into consideration, since the surfactant f...

Journal: :Langmuir : the ACS journal of surfaces and colloids 2014
Hiromichi Nakahara Yui Kojima Yoshikiyo Moroi Osamu Shibata

Solubilization of benzene, toluene, ethylbenzene, n-propylbenzene, n-butylbenzene, and n-pentylbenzene into micelles of decanediyl-1-10-bis(dimethyltetradecylammonium bromide) (14-10-14,2Br(-)) has been investigated in the temperature range from 288.2 to 308.2 K. The equilibrium concentrations of all the solubilizates are determined spectrophotometrically. The concentration of the solubilizates...

2010
Stefana-Oana Purcaru Mihaela Ionescu Cristina Raneti Valentina Anuta I. Mircioiu Ionela Belu

Nimesulide is a weakly acidic non-steroidal anti-inflammatory drug (NSAIDs). Like many non-steroidal anti-inflammatory drugs, Nimesulide is very sparingly soluble in water (≈ 0.01 mg/mL).The poor aqueous solubility and wettability of Nimesulide gives rise to difficulties in pharmaceutical formulations for oral or parenteral delivery, which may lead to variable bioavailability. Based on the Biop...

2013
Ali Reza Tehrani-Bagha Krister Holmberg

In this paper, the use of surfactants for solubilization of hydrophobic organic dyes (mainly solvent and disperse dyes) has been reviewed. The effect of parameters such as the chemical structures of the surfactant and the dye, addition of salt and of polyelectrolytes, pH, and temperature on dye solubilization has been discussed. Surfactant self-assemble into micelles in aqueous solution and bel...

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