Liquid-liquid extraction is an alternative method that can be used for desulfurization and denitrification of gasoline and diesel fuels. Recent approaches employ different ionic liquids as selective solvents, due to their general immiscibility with gasoline and diesel, negligible vapor pressure, and high selectivity to sulfur- and nitrogen-containing compounds. For that reason, five imidazolium...

The contamination of sulfur emanating from pyrrhotite in magnetite concentrates has been a problem in iron ore processing. This study utilized froth flotation to float pyrrhotite away from magnetite using collectors of xanthate and dixanthogen. It was found that xanthate or dixanthogen alone could not achieve selective separation between pyrrhotite and magnetite in flotation. A high loss of mag...

We present a novel strategy for the traceless purification and synthetic modification of peptides and proteins obtained by native chemical ligation. The strategy involves immobilization of a photocleavable semisynthetic biotin-protein conjugate on streptavidin-coated agarose beads, which eliminates the need for tedious rebuffering steps and allows the rapid removal of excess peptides and additi...

in the present study, removal of dibenzothiophene (dbt) from model oil (n-hexane) was investigated using magnetic activated carbon (mac) nano-composite adsorbent. the synthesized nano-composite was characterized by ft-ir, fe-sem, bet and vsm techniques. the mac nano-composite exhibited a nearly superparamagnetic property with a saturation magnetization (ms) of 29.2 emu g-1, which made it desira...

in this research, zeolite-tio2 nanocomposite was prepared for degradation of dibenzothiophene as a typical aromatic organosulfur compound of transportation fuels.the synthesized tio2 was immobilized on the surface of clinoptilolite by solid state dispersion (ssd) method. the nanocomposite was then characterized by xrd, ftir, tem and sem techniques. photodegradation of dibenzothiophene in n-hexa...

The application of imidazolinium and amidinium salts as soft Lewis acid organocatalysts is described. These salts were suitable catalysts for the activation of unsaturated thioesters in a Diels-Alder reaction and in the ring opening of thiiranes and epoxides. The products were isolated in good yields. The mild catalysts did not cause desulfurization of the products containing a thiol or thiocar...

Short phosphorothioate oligonucleotides have been prepared by refluxing an equimolar mixture of thymidine and triethylammonium phosphite in toluene in the presence of elemental sulfur. Desulfurization and subsequent digestion of the products by P1 nuclease revealed that nearly 80% of the internucleosidic linkages thus formed were of the canonical 3´,5´-type.

An unusual ceria dispersion was achieved by using the confined space between template and silica walls in as-prepared mesoporous silica, for the first time. The new adsorbents exhibit high adsorptive desulfurization activity and, more importantly, excellent stability and reusability, which is impossible to realize with conventional adsorbents.