a simple, precise, inexpensive and sensitive voltammetric method has been developed for the determination of gemifloxacin mesylate (gem) in the presence of tween 80 in the bulk, farmaceutical dosage forms and human urine at gold nanoparticles modified carbon paste electrode (gncpe). the electrochemical behavior of gem has been investigated by using cyclic voltammetry (cv) and differential pulse...

The van der Waals (vdW) interactions of n-alkanethiols (ATs) adsorbed on planar Au(111) and Au(100) surfaces and curved Au nanoparticles of different diameters are reported. By means of electrochemical measurements and molecular dynamic calculations, the increase in the average geometrical curvature of the surface influences the global interactions, that is, decreasing vdW interactions between ...

according to environmental protection organization of iran, maximum permissible concentration of residual phosphorus in treated municipal wastewater is 1 mg /l-p. the total average phosphorus concentration in raw municipal wastewater is about 8 mg / l; about 70 percent of the incoming phosphorus normally is discharged with secondary treatment plant effluents. in this research, the role of addin...

one of the problems in the case of stainless steels is their low corrosion resistance against pitting corrosionin chloride containing environments, thereby leading to severe damage to industries. in this research, the pitting corrosion of 304 austenitic stainless steel was studied in 3.5% nacl solution at room temperature (25˚c) by performing electrochemical measurements (containing cyclic pola...

in the present paper, the use of a novel carbon paste electrode modified by 7,8-dihydroxy-3,3,6-trimethyl-3,4-dihydrodibenzo[b,d]furan-1(2h)-one (dtd) and oxidized multi-walled carbon nanotubes (ocnts) is described for determination of levodopa (ld), acetaminophen (ac) and tryptophan (trp) by a simple and rapid method. at first, the electrochemical behavior of dtd is studied, then, the mediated...

in this work, modification of carbon paste electrode surface with poly (2, 5-dimethyl aniline) (p-2,5-dma) by using electrochemical polymerization was described. then, transition metal ions of ni(ii) were incorporated into the polymer film by two ways. at first way, the polymeric modified electrode was immersed in 0.2 m niso4 solutions and the second way was carried out by electrodeposition of ...

In this paper the electrodeposition of nickel on n-Si(111):H substrate, in the presence of sulphuric acid, was studied. Cyclic voltammetry has been used to characterize the electrochemical behavior of the system. The nickel deposits had a flower-like morphology with the sphericalnanostructure nucleus, distributed uniformly on the surfaces of the prepared n-Si(111) substrate.

An overview is given of the anomalous behavior of some metals, in particular Fe and Cr, in acidic aqueous solutions during anodic dissolution. The anomaly is recognizable by the fact that during anodic dissolution more material dissolves than would be expected from the Faraday law with the use of the expected valence of the formed ions. Mechanical disintegration, gas bubble blocking, hydrogen e...

Aprotic rechargeable Li-O2 batteries are currently receiving considerable interest because they can possibly offer significantly higher energy densities than conventional Li-ion batteries. The electrochemical behavior of Li-O2 batteries containing bis(trifluoromethane)sulfonimide lithium salt (LiTFSI)/tetraglyme electrolyte were investigated by galvanostatic cycling and electrochemical impedanc...