this work is aimed to evaluate the role of nanoclay in the protective performance of an eco-friendly silane sol-gel layer applied on mild steel substrate in 0.1m sodium chloride solution. at the first step, the effect of ph of the silane solution, consisting of a mixture of γ-glycidoxypropiltrimethoxysilane and methyltriethoxysilane and tetraethoxysilane, on the coating performance was evaluate...

the present study concentrates on the synthesis of au nanoparticles (aunps) using aqueous solution of polyvinylpyrrolidone (pvp) and tetrachloroaurate by different methods as thermal, sonochemical and electrochemical reduction. the pvp has been used as a reducing agent and acts as a stabilizer for au nano particles that obtained as principal product. in all synthesis procedures, the active radi...

High pressure–high temperature (HP/HT) methods are utilized to introduce structural modifications in the layered lithium transition metal oxides LiCoO2 and Li[NixLi1/3 2x/3Mn2/3 x/3]O2 where x 1⁄4 0.25 and 0.5. The electrochemical property to structure relationship is investigated combining computational and experimental methods. Both methods agree that the substitution of transition metal ions...

This contribution is based on our presentation at the 1 International Symposium on Sensor Science, Paris, 16-20 June 2003. It presents recent results regarding the electrochemical determination of submicromolar and nanomolar concentrations of various carcinogenic substances (nitrated polycyclic aromatic hydrocarbons, heterocyclic compounds, azo compounds, aromatic amino compounds, etc.) using b...

Article can be accessed online on: www.ijpsr.com ABSTRACT: The determination of drugs in pharmaceutical preparations and biological fluids is of pivotal importance in the pharmaceutical and medical sciences. Successful analysis requires sensitivities at ppb level or even less in biological fluids with high selectivity and minimal interferences from various artifacts. Till recently, biopharmaceu...

1. Theoretical considerations lead to the conclusion that dissociable acidic groups present to a varying extent in different collodion preparations determine the electrochemical behavior of membranes cast from these preparations. It is further reasoned that the base exchange capacity of the collodion surfaces is the true quantitative measure of the abundance of the dissociable groups. 2. The co...

Electrochemistry (EC) is a mature scientific discipline aimed to study the movement of electrons in an oxidation-reduction reaction. EC covers techniques that use a measurement of potential, charge, or current to determine the concentration or the chemical reactivity of analytes. The electrical signal is directly converted into chemical information. For in-depth characterization of complex elec...

This paper proposes the application of Gaussian process regression (GPR) as an alternative regression model to resolve the hard overlapped electrochemical signals belonging to the 2,4,6trichlorophenol/2,6-dichlorophenol (TCP/DCP) system. Gaussian process derives from the perspective of Bayesian non-parametric regression methods, in terms of the parameterization of the covariance function, resul...