Hemin/G-quadruplex-based DNAzyme concatamers were utilized as electrocatalysts and biolabels to construct a sandwich-type electrochemical immunosensor for sensitive detection of IgG1 (as a model analyte).

Progression of technology nodes in integrated circuit design is only possible if there are sustainable, cost-efficient processes by which these designs can be implemented. As future technologies are increasing device density, shrinking device dimensions, and employing novel structures, semiconductor processing must also advance to effectively and efficiently process these devices. Arguably one ...

In this study, the internal resistance with the increasing of electrode thickness in a typical nanoporous carbon-based supercapacitor and their corresponding electrochemical performances were designed and investigated in detail. As for the carbon-based double electrode layer electrochemical system, electrochemical experiments greatly support the fact of nonlinear dependence and indicate that th...

Ammonia is exclusively synthesized by the Haber-Bosch process starting from precious carbon resources such as coal or CH4. With H2O, H2 is produced and with N2, NH3 can be synthesized at high pressures and temperatures. Regrettably, the carbon is not incorporated into NH3 but emitted as CO2. Valuable carbon sources are consumed which could be used otherwise when carbon sources become scarce. We...

The corrosion inhibition effect of N,N′-bis(n-Hydroxybenzaldehyde)-1,3-Propandiimine on mild steel has been investigated in 1 M HCl using electrochemical impedance spectroscopy. A predictive model was presented for Nyquist plots using an artificial neural network. The proposed model predicted the imaginary impedance based on the real part of the impedance as a function of time. The model to...

Articular cartilage exhibits complex mechano-electrochemical behaviour due to its anisotropy, inhomogeneity and material non-linearity. In this work, the thickness and radial dependence of cartilage properties are incorporated into a 3D mechano-electrochemical model to explore the relevance of heterogeneity in the behaviour of the tissue. The model considers four essential phenomena: (i) osmoti...

Metallic materials in practical use are normally exposed to corrosion in the atmospheric and aqueous environments. Metallic corrosion is one of the problems we have often encountered in our industrialized society; hence it has been studied comprehensively since the industrial revolution in the late eighteenth century. Modern corrosion science was set off in the early twentieth century with the ...

An understanding of the doping and ion distributions in light-emitting electrochemical cells (LECs) is required to approach a realistic conduction model which can precisely explain the electrochemical reactions, p-n junction formation, and ion dynamics in the active layer and to provide relevant information about LECs for systematic improvement of function and manufacture. Here, Fourier-transfo...

In the present study, the operating conditions of an anode-supported high temperature direct internal reforming (DIR) planar solid oxide fuel cell (SOFC) are numerically analyzed. SOFCs are the energy conversion devices that produce electricity and heat directly from a gaseous fuel by the electrochemical combination of that fuel with an oxidant. A planar SOFC consists of an interconnect structu...

A model has been developed for calculating the rates of general corrosion of carbon steel and 13%Cr steel in aqueous systems containing carbon dioxide, hydrogen sulfide and other components. The model combines a comprehensive thermodynamic speciation module with electrochemical computations based on the mixed-potential theory. The electrochemical calculations recognize the effects of various pa...