In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of ...

TWC modes. Results indicate that the oceanic evolution for both modes is consistent with wind stress induced verticallyintegrated, meridional mass transport into and out of the equatorial Pacific—i.e. a charging and discharging of the equatorial Pacific—despite having distinctly different wind stress anomaly patterns. The process-based similarity between these two modes of tropical Pacific wind...

The relationship between axial length and equatorial diameter and eye volume has been studied in 4 groups of eyes: intact emmetropic eyes, emmetropic eyes with retinal detachment, eyes with moderate myopia and retinal detachment, and eyes with high myopia and retinal detachment. It was found that eyes with detached retinas, regardless of whether they are myopic or emmetropic, are of significant...

[1] Mixing in the ocean plays a key role in the ocean’s dynamics and thermodynamics and how the ocean interacts with the atmosphere. Here we focus on lateral mixing in the equatorial ocean, and in particular the part played by inertial instability. We demonstrate the effectiveness of the instability in promoting mixing in the equatorial thermocline, that is sufficient to affect the large scale ...

The paper discusses the reasons for tension between Nigeria and Equatorial Guinea over the past decades. Although the presence of the Nigerian labour force in Equatorial Guinea has been considered the principal source of tension, the paper argues that power politics should not be excluded. The relatively weak position of Equatorial Guinea as a neighbour of populous and wealthy Nigeria might hav...

In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three benzene rings make dihedral angles of 87.83 (17),...

Catalytic osmylation of cis and trans 2-cyclohexene-cyclohexanol (1a) and (1b) are carried out in the presence of N-methyl morpholine-N-oxide. Under the same conditions, only the cis isomer reacted, leading to triol (3). The steric hindrance of the equatorial OH group probably prevents the trans isomer from entering into such reaction. Triol (3) was also obtained from the reduction of the d...

Ab initio HF/6-31G* Methode was employed to calculate the bond length in 2- phosphinanes when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2- boromo substituented phosphinanes. The effect of anomeric effec...

Ab initio HF/6-31G* Methode was employed to calculate  the bond length in 2- phosphinanes  when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of  the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2-boromo substituented phosphinanes. The effect of anomeric eff...