In this work we report on the electrochemical behavior of Ce(IV)/Ce(III) redox couple in pure N,N-dialkyl amides (N,N-DA), namely N,N-di(2-ethylhexyl)-n-butanamide (DEHBA), N,N-di(2-ethylhexyl)-iso-butanamide (DEHiBA), and N,N-di(2-ethylhexyl)-3,3-dimethyl butanamide (DEHDMBA) equilibrated with nitric aqueous solutions as an entry to direct characterization plutonium these extractants. process ...

two n4-type schiff base ligands named n,n'-bis(2-pyridylmethylidene)-1,2-diiminoethane (l1) and n,n'-bis(2-pyridylmethylidene)-1,3-diiminopropane (l2) have been synthesized by the reaction of pyridine-2-carbaldehyde with ethylenediamine and propylenediamine, respectively. the binding abilities of l1 and l2 in dichloromethane towards cu2+, cd2+, co2+, ni2+, zn2+ and pb2+ ions were evaluated by p...

Purification of concentrated manganese sulfate solution by solvent extraction is discussed in this paper. The use bis(2-ethylhexyl) hydrogen phosphate (D2EHPA) and bis(2,4,4-trimethylpentyl)phosphinic acid (BTMPPA) was studied removal impurities from zinc electrowinning anode sludge leachates. Over 99 % iron were removed both extractants at around pH 3 two mixer-settlers operating continuous co...

During the operation of oil-filled electrical equipment under influence temperature, humidity and other negative factors, destruction paper insulation occurs. As a result this destruction, furan compounds are formed, which get into transformer oil. To identify process insulation, control in oil is carried out by instrumental methods. Of these methods, most widely used gas chromatography using p...