Loss of lithium in the initial cycles appreciably reduces the energy density of lithium-ion batteries. Anode prelithiation is a common approach to address the problem, although it faces the issues of high chemical reactivity and instability in ambient and battery processing conditions. Here we report a facile cathode prelithiation method that o ers high prelithiation e cacy and good compatibili...

Recently emerging potassium ion (K-ion) batteries offer a lower-cost alternative to lithium-ion batteries while enabling comparably high storage capacity. Here, we leverage the strong Raman spectroscopic response of few-layered graphene to provide the first insight into the electrochemical staging sequence for K+ ions in graphitic carbons. Our analysis reveals the signature of a dilute stage I ...

We report the first successful demonstration of an optical microelectromechanical systems (MEMS) sensing platform for the in situ characterization of electrochemically induced reversible mechanical changes in lithium-ion battery (LIB) electrodes. The platform consists of an array of flexible membranes with a reflective surface on one side and a thin-film LIB electrode on the other side. The mem...

Lithium ion batteries (LIBs) have dominated the portable electric market over decades; however, limited and unevenly distributed lithium resources induce concerns on their future large-scale applications. Increasing efforts been endeavored exploring post-Li batteries, such as Na-ion, K-ion, Al-ion Mg-ion due to high abundance of corresponding elements in Earth crust. Manufacturing reliable elec...

Abstract The rational design of dense and flexible solid-state electrolytes (SSEs) with interface compatibility is still challenging. Here, we report a three-layer 3D nanofibrous matrix (PCOF) by constructing nanofiber framework combining polyacrylonitrile (PAN) fast Li-ion conductor covalent organic frameworks (COFs) electrospinning method. PCOF film can maintain an extraordinary electrolyte/e...

Flexible butyl interconnection segments are synthetically incorporated into an electronically conductive poly(pyrene methacrylate) homopolymer and its copolymer. The insertion of butyl segment makes the pyrene polymer more flexible, and can better accommodate deformation. This new class of flexible and conductive polymers can be used as a polymer binder and adhesive to facilitate the electroche...

3,7-Disubstituted N-ethylphenothiazine derivatives were synthesized as redox shuttle candidates for lithium-ion batteries. Battery cycling results show that three derivatives prevent overcharge.

Correction for 'Highly lithium-ion conductive battery separators from thermally rearranged polybenzoxazole' by Moon Joo Lee et al., Chem. Commun., 2015, 51, 2068-2071.

The development of high capacity and long-life lithium-ion batteries is a long-term pursuing and under a close scrutiny. Most of the researches have been focused on exploring electrode materials and structures with high store capability of lithium ions and at the same time with a good electrical conductivity. Thermal conductivity of an electrode material will also have significant impacts on bo...

The market of grid-level electricity storage is growing rapidly, with a predicted market value of 1.6 billion in 2012 and 8.3 billion in 2016. Electrochemical storages such as lead-acid, nickel-cadmium, sodium-sulfur and lithium-ion batteries are candidates with high potential for grid-level implementations. Among them, sodium-sulfur battery appears to be suitable for energy application while l...